CROSS CANNIZZARO reaction and Intramolecular Cannizzaro Reaction : Part-2: Difficult cases
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- เผยแพร่เมื่อ 12 ต.ค. 2024
- This is an important reaction of Organic Chemistry: Cannizzaro Reaction
The video is in four parts: (a) basics of Cannizzaro reaction
(b) cross cannizzaro and intramolecular cannizzaro: Simple cases
(c) cross cannizzaro and intramolecular cannizzaro: Difficult cases with an awesome Trick to solve them
(d) Detailed mechanism of Cannizzaro reaction
Quick Look:
Awesome Trick: 3:34
Examples from 5:03
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Sir one doubt ...in cannizaro RDS is transfer and acceptance of h minus so the substrate which acccepts the h minus fastest will be more reactive thus electron deficient shall accept h minus faster so electron deficient must be reduced and electron rich oxidized ..we shall decide the product by rds and not first attack of oh minus ..please correct me sir if my logic is wrong
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sir why 4-methylacetanilide on reaction with FeBr3/Br2 gives chief product as the one in which bromine atom is ortho to amide group and meta to methyl group as given in morrison boyd what i think that this product is not feasable as due to steric reasons attack should take place at ortho to methyl group or does it have any thing to do with diffrence in activating nature of the two substituents
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Sir one small doubt if there is adjacent carbonyl/or a carbocation at alpha position
Which is more electron rich ?
An benzylic adjacent group
Or a tertiary carbon
Because in case of carbocation
3⁰ is more stable than benzylic
plazma CHAZE
Benzylic Group adjacent to a carbocation gives better stability to it than an adjacent tertiary carbon.
Latter cannot show Hyperconjugation, while the tertiary carbocation was stabilised by HC.
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