I will say, your ability to articulate what is going on in the chemical reactions without pause and thought is getting a lot better. You're maturing as a chemist and I attribute this to your PhD. Keep at it man. How is it going BTW?
Hey, I'm glad you think so. I think that's maybe its me getting better with saying things and then editing it down correctly. Cut down enough so that you don't waffle and its boring, but not so cut down that you become hard to understand because you skip stuff or assume a lot of knowledge. Always a hard balance to walk. The PhD is going okay, thanks for asking! I've hit the half way mark for my project and while the main project isn't doing that great..... ive got some interesting pet side projects that I think are more interesting than the main one lol. The main project requires spectroscopic scans of energetic materials, but so far we're still applying for the permits for these materials.... its been months of paperwork. For stuff I have at home, but that's not exactly allowed so doing it all 'correctly' takes.... a very long time. Which is frustrating. So it feels even better to get into the home chem lab and have some success! Glad I can still find the time, for now!
@@ExtractionsAndIre Just curious, what materials do you need permits for? And what are the permits called? I live in the US so it wont apply to me, but I'm just curious what you have to go through to get which chemicals/materials.
@@notinsane4165 do it in a lab coat and goggles with preferably an Australian or Norwegian accent. Cause for some reason those are the most friendly sounding. Tho a nasally voice in general can substitute.
I love how every video he's like "we're just going to copy this exactly because it worked pretty well" then immediately tells you some basic component that he's switching out on the assumption it'll work.
I did the same Sythesis and it is originally from a Paper from S. M. Jörgensen (1894). I think the reason why your yield was better was, that you kinda protected it from light by wrapping it while you boiled it. I did got a yield of 75% by protecting it as good as possible from light. At the end of the paper Jörgensen mentions, that the complex is sensitive to light, when in solution. So I put a small amount of my product in water and let it sit for a day (one in the dark, one in the light) and the one in the light turnt to a dark brownish color (the other one did not change). 🤷🏼♀️
I like the more calm vibes in this video. I also like the explosions and fire chaotic vibes. They are both really nice styles that fit well to their respective content.
@33Ddg209Ret7 there were two track yeah, and I forgot to put the names of the tracks in! I'll do that in a sec. They're both early Aphex Twin (from his soundcloud dump of unclaimed tracks), from around the first selected ambient works album
I honestly thought I was entering Draynor Village but it just kept looping and left me uneasy. Edit: actually it’s the Lumbridge Swamp (Book of Spells is the OSRS track) but you know what that’s close enough for me.
Dude, Aphex Twin + Chemistry? You get an instant sub! 0:24 I am quite surprised TH-cam recommended this video to me, given this. Either your 'accent' didn't trigger the robots, or they're slackin on the job. Either way, I'm glad our algorithmic overlord linked you to me via this video. I look forward to exploring your catalog of videos, both past and future.
Hey mate, thanks for all your effort and time making these videos. Your channel gets me so stoked on my own studies, you're a chemistry beast! Keep up the awesome work, I hope your PhD is going well. Cheers
I really don't know much about chemistry but I have always found it interesting. Your videos are very entertaining, you make chemistry very interesting. I wish I would've had a teacher like you back in high school.
Right on TDep! I *LOVE* transition metal chemistry. It's what I've been working with when I'm not trying to make more Silver Azide! I really need to expand to Cobolt as Manganese and permanganates (while being totally cool) is starting to run its course with me.
Gorgeous! I love transition metal chemistry xD If we were only looking at playing the odds, there are more chances of the ligands re-coordinating in the cis arrangement. But it does make sense that, when the ligands rearrange themselves, trans is favored. The anions as far apart as possible and it avoids having the slightly bulkier NH3 from having an instance of being 90° from three other NH3s.
excellent demonstration of synthesis, it's a common procedure in the inorganic chemistry lab on UNAM's chemistry school. I have a obsevation about the structure of the complex at the begining of the video. the carbonate ion don´t forms chelated rings of four members because the overtention of the angles; however carbonate ion can forms binuclear complexes with two carbonate bridges between cobalts. Again excellent video!!!
Oh, I’ve actually seen preparation of this complex in my highschool lab. But as far as I remember, most people, who tried it, just got a dark-brown solution without any solids formation.
Nice safe measuring cylinder around 5:04. I don’t know if you have looked around much. But there is some good deals on glassware. I am a research student myself. Glassware from sigma is a CRIME. If you want a heap of cheap beakers go see wiltronics (australia). Westlabs and labgear are also reasonable for other glassware.
Westlabs used to sell to me (It's where I got my hotplate from) but then they deleted my account and you need to get approved to have an account... sad. But yeah, Sigma is always heaps expensive. Chinese glassware is dramatically cheaper, for not much a drop in quality. Thanks for those reccomendations tho!
Extractions&Ire that sucks. Any glassware in particular you looking for still? I know there is some glassware we have excessive amounts of and just collects dust in draws or containers. Can liase via other means if necessary
2:03 How do you make those neat graphics? Any specific program? Im not talking about the awesome chalk board molecular art, if that wasn't clear... :-P
The program is called Mercury, it allows you to download CIF files and then generate animations. It's a little bit of work, but I agree, it can come off pretty neat!
I thought I was going to make an original joke about the lack of yellow chemistry but it appears I’m not so original... oh well, great vid, pretty colors, 10/10
Extractions&Ire yes the colors were fantastic! To be honest one of the main reasons I’m pursuing a chemistry degree is I just like to mix stuff and see pretty colors. That and blowing things up. I’m sure you can relate ;)
A wine bottle of ammonia solution. Fantastic. Also, you mentioned that the peroxide oxidises the Cobalt to its +3 oxidation state, but the structure you drew is Co(II). If this oxidation then reduction happens, what is reducing the Cobalt? And finally, the blue solution you have at the end is likely [NH4]2[CoCl4]. Nice video though!
How could you tell it was Co(III) in the structure? And also yeah, okay that's a cool complex. It was a very nice blue. I think the hexachloro complex is a nice blue too? So maybe a mix
@@ExtractionsAndIre well carboxylate is a 2- X-type ligand and the ammine ligands are obviously neutral L-type ligands, so to have a neutral complex, it's got to be a Co(II) centre.
Very nice video! I wonder about several points though: 1) what gas is produced after you added hydrogen peroxide? 2) what gas is produced when you are adding extra carbonate salt? 3) Doesn't ammonia carbonate decompose when heated, or in solution this doesn't work like that? Thank you!
I loved it (as always)! I believe I remember you saying that you dispose of your waste at a professional waste disposal facility. How much does that cost?
I must have said that I intend to one day.... I keep all the transition metal waste segregated, and one day ill drop it all off. But never done it yet!
@@ExtractionsAndIre If you ever do, let us know how it goes! Also, how much of your chemistry do you do illegally? I always want to do more home chemistry, but I am concerned about unintentionally breaking laws. Not trying to have the ATF throw me in jail for the next 20 years.
Is the carbonate technically a chelate type formation? I.e. claw. Something like EDTA, occupying to lig and positions? PS love your work… Is it possible to do a one-off page on payment? To watch enough, but would love to see you rig it out/have more fun.
i really like your videos :D but you should consider building a fume hood so you can work better and saver. i build mine using a tube ventilator and an acrylic glass box that i self assembled. stay save and have fun mfg hazelChem
@@ExtractionsAndIre , no worries man. It happens. Just don't be like me and take down a video for a grammatical error that was mkst likely an auto correct issue. Lol! We still love ya! ;)
What's the music? I really like it EDIT: Oh ok they're: 1. "Sams car" 2. "19 Ssnb" From Aphex Twin. Search for "selected SoundCloud works" or "selected ambient works vol 3" Thanks, Fedor Golishevskiy! You said you would put this info in there "In a sec". That was yesterday. ^^
Very non-yellow. Congrats on the successful reaction.
Yes its pigs blood red
I will say, your ability to articulate what is going on in the chemical reactions without pause and thought is getting a lot better. You're maturing as a chemist and I attribute this to your PhD. Keep at it man. How is it going BTW?
agreed!
Hey, I'm glad you think so. I think that's maybe its me getting better with saying things and then editing it down correctly. Cut down enough so that you don't waffle and its boring, but not so cut down that you become hard to understand because you skip stuff or assume a lot of knowledge. Always a hard balance to walk.
The PhD is going okay, thanks for asking! I've hit the half way mark for my project and while the main project isn't doing that great..... ive got some interesting pet side projects that I think are more interesting than the main one lol. The main project requires spectroscopic scans of energetic materials, but so far we're still applying for the permits for these materials.... its been months of paperwork. For stuff I have at home, but that's not exactly allowed so doing it all 'correctly' takes.... a very long time. Which is frustrating.
So it feels even better to get into the home chem lab and have some success! Glad I can still find the time, for now!
@@notinsane4165 ive always thought: you say it best when you say nothing at all
@@ExtractionsAndIre Just curious, what materials do you need permits for? And what are the permits called? I live in the US so it wont apply to me, but I'm just curious what you have to go through to get which chemicals/materials.
@@notinsane4165 do it in a lab coat and goggles with preferably an Australian or Norwegian accent. Cause for some reason those are the most friendly sounding. Tho a nasally voice in general can substitute.
I love how every video he's like "we're just going to copy this exactly because it worked pretty well" then immediately tells you some basic component that he's switching out on the assumption it'll work.
Metal chemistry makes pretty colours, organic chemistry is smelly, colourless, but sometimes goes yellow.
Or sometimes even brown/black. Isn't that wonderful?
Yeah but inorganic chemistry is just a gross topic to learn about when compared to organic chemistry
@@cwill2127 explain?
@@bentroyer1 inorganic bad. No fun. Dangerously not fun amount of physics hidden in it.
O-chem fun. Patterns. No math. No bad.
I'm assuming organic is the one that yields psychadelic compounds... so that's the winner.
I did the same Sythesis and it is originally from a Paper from S. M. Jörgensen (1894). I think the reason why your yield was better was, that you kinda protected it from light by wrapping it while you boiled it. I did got a yield of 75% by protecting it as good as possible from light. At the end of the paper Jörgensen mentions, that the complex is sensitive to light, when in solution. So I put a small amount of my product in water and let it sit for a day (one in the dark, one in the light) and the one in the light turnt to a dark brownish color (the other one did not change). 🤷🏼♀️
I like the more calm vibes in this video. I also like the explosions and fire chaotic vibes. They are both really nice styles that fit well to their respective content.
I get so excited when Extractions&Ire or Explosions&Fire2 post a new video.... _NOBODY BOTHER ME FOR THE NEXT 12 MINUTES AND 15 SECONDS!_
Awesome success! Glad it didn't go yellow for some inexplicable reason.
the music made this a very odd exprience, kind of an oddly serene video
@33Ddg209Ret7 there were two track yeah, and I forgot to put the names of the tracks in! I'll do that in a sec. They're both early Aphex Twin (from his soundcloud dump of unclaimed tracks), from around the first selected ambient works album
The chemplayer computer voice in the background made odd too lol
I honestly thought I was entering Draynor Village but it just kept looping and left me uneasy.
Edit: actually it’s the Lumbridge Swamp (Book of Spells is the OSRS track) but you know what that’s close enough for me.
1. "Sams car"
2. "19 Ssnb"
Search for "selected SoundCloud works" or "selected ambient works vol 3"
@@ExtractionsAndIre RIP Chemplayer, it was nice nostalgia for sure.
Dude, Aphex Twin + Chemistry? You get an instant sub!
0:24 I am quite surprised TH-cam recommended this video to me, given this. Either your 'accent' didn't trigger the robots, or they're slackin on the job. Either way, I'm glad our algorithmic overlord linked you to me via this video. I look forward to exploring your catalog of videos, both past and future.
Metal ion chem is beautiful. I have been making all sorts of stuff from it simply for the colors. Copper makes my favorite blue and green.
Hey mate, thanks for all your effort and time making these videos. Your channel gets me so stoked on my own studies, you're a chemistry beast! Keep up the awesome work, I hope your PhD is going well. Cheers
Colors! And to top it off you taught me some stuff about the structure of Co compounds I didn’t know. Very cool vid. Good work and great yield!
No tar, not yellow. Is it even chemistry? Zero stars.
yep
Transition metals and their lovely colorfull chemistry, always a pleasure to see!
8:51 "wash with a little ICE cold water and dry thoroughly OFF a PUMP" we miss you ChemPlayer
they are on bitchute
Fedor Golishevskiy I know
I really don't know much about chemistry but I have always found it interesting. Your videos are very entertaining, you make chemistry very interesting. I wish I would've had a teacher like you back in high school.
Damn you've grown since last video I saw.
Glad to see your chemistry and channel is going well.. :)
You suck zumbit. Just sayin
Oh wait. Your Zubmit. Allgood.
Thought I'd finally run into this guy zumbit who stole all my diamonds on my servers
Transition metals don't often get the attention they deserve.
Very cool video, definitely some fun chemistry!
I fucking love you Tom. You became a doctor and then made chemistry so god damn understandable. I fucking love you mate. God speed.
Right on TDep! I *LOVE* transition metal chemistry. It's what I've been working with when I'm not trying to make more Silver Azide! I really need to expand to Cobolt as Manganese and permanganates (while being totally cool) is starting to run its course with me.
Cobalt is a fantastic element to do chemistry with. It won't do the things silver azide can do though!
I like the casual "cooking" in there at the beginning.
French Canada here... great vids. Keep it up if it makes you happy! J'aime comment tu fais tes videos.
Chemistry that's colors other than yellow!
[[PLATINUM WANTS TO KNOW YOUR LOCATION]]
The Yellow always finds me eventually
thank you so much for confirming to me that carbonato is the way to properly describe a carbonate ligand
This was some good stuff! Definitely do more transition metal chem!
Best way to finish weekend with extractions&ire video
Gorgeous! I love transition metal chemistry xD
If we were only looking at playing the odds, there are more chances of the ligands re-coordinating in the cis arrangement. But it does make sense that, when the ligands rearrange themselves, trans is favored. The anions as far apart as possible and it avoids having the slightly bulkier NH3 from having an instance of being 90° from three other NH3s.
When you spooned the cobalt sulfate out of the bag, it looked like a dry spice mix.
nutritious and delicious
@@ExtractionsAndIre its not Yellow Chem, how bad could it be?
Keep up the great work mate!
I love cobalt and chromium chemistry for all the crazy colors they go through.
Some absolutely bangin' music in this one, m8
excellent demonstration of synthesis, it's a common procedure in the inorganic chemistry lab on UNAM's chemistry school. I have a obsevation about the structure of the complex at the begining of the video. the carbonate ion don´t forms chelated rings of four members because the overtention of the angles; however carbonate ion can forms binuclear complexes with two carbonate bridges between cobalts. Again excellent video!!!
Pouring chemicals from a vodka bottle into a broken beaker is the only science i want to see from now on
Yaaaaaayyyyy he's back ❤️😍❤️😍❤️😍❤️😍❤️😍🙏
The way it goes from pink to blue as it goes from cis to trans is quite poetic
loved the purple foam when the final H202 was added
It was beautiful to watch!
I have no idea what you are talking about 99% of the time, but I like seeing chemicals 'n stuff
Oh, I’ve actually seen preparation of this complex in my highschool lab. But as far as I remember, most people, who tried it, just got a dark-brown solution without any solids formation.
Maybe that week of uninterrupted crystallization was real good!
lovely project, sweet tracks! Cheers!
You missed the third hydrogen on the ammonias in the 3d structure!
I missed the third hydrogens on the ammonias everywhere, this is a mistake oops
... and thank you for pronouncing ligand properly.
I love the broken volumetric beaker
thought I read 'anime' in the title and did a triple take
Cook some cobalt chloride eggs benedict
deep fried cobalt
Mmmm bacon carbonato
Carcinoma benedict!
@@californium-2526 benedict carbonbatch!
A very complex recipe there
Nice safe measuring cylinder around 5:04. I don’t know if you have looked around much. But there is some good deals on glassware. I am a research student myself. Glassware from sigma is a CRIME. If you want a heap of cheap beakers go see wiltronics (australia). Westlabs and labgear are also reasonable for other glassware.
Westlabs used to sell to me (It's where I got my hotplate from) but then they deleted my account and you need to get approved to have an account... sad. But yeah, Sigma is always heaps expensive. Chinese glassware is dramatically cheaper, for not much a drop in quality.
Thanks for those reccomendations tho!
Extractions&Ire that sucks. Any glassware in particular you looking for still? I know there is some glassware we have excessive amounts of and just collects dust in draws or containers. Can liase via other means if necessary
Much nicer than yellow chemistry 😂
Not a single shred of yellow in this video and it's glorious
The music was a really nice touch
2:03 How do you make those neat graphics? Any specific program?
Im not talking about the awesome chalk board molecular art, if that wasn't clear... :-P
The program is called Mercury, it allows you to download CIF files and then generate animations. It's a little bit of work, but I agree, it can come off pretty neat!
@@ExtractionsAndIre For sure, actually seeing it rotate as opposed to just a 3d rendering that stays still is pretty fantastic.
I made chloropentaamminecobalt chloride last week, beautiful red violet crystals.
At least you credit to all chemistry for giving you the idea. Most people don't do things like that anymore.
This was lovely.
Wow. Now this was a seriously cool chemy chem vid, and it wasn't yellow!
Awesome video!
Watching this before my chem exam tomorrow
Good luck!!
I wrote mine today
I like your custom 80mL graduated cylinder
Those crystals were so sparkly!!!!🤩
them chemplayer feels @ 8:53 tho
The feels ಥ_ಥ
Is Chemplayer's music free? Would be cool to mix in from time to time.
I thought I was going to make an original joke about the lack of yellow chemistry but it appears I’m not so original... oh well, great vid, pretty colors, 10/10
I didn't even mention it in the video, I should've! It was a very yellow-free synthesis
Extractions&Ire yes the colors were fantastic! To be honest one of the main reasons I’m pursuing a chemistry degree is I just like to mix stuff and see pretty colors. That and blowing things up. I’m sure you can relate ;)
Fabulous video.
A wine bottle of ammonia solution. Fantastic.
Also, you mentioned that the peroxide oxidises the Cobalt to its +3 oxidation state, but the structure you drew is Co(II). If this oxidation then reduction happens, what is reducing the Cobalt?
And finally, the blue solution you have at the end is likely [NH4]2[CoCl4].
Nice video though!
How could you tell it was Co(III) in the structure?
And also yeah, okay that's a cool complex. It was a very nice blue. I think the hexachloro complex is a nice blue too? So maybe a mix
@@ExtractionsAndIre well carboxylate is a 2- X-type ligand and the ammine ligands are obviously neutral L-type ligands, so to have a neutral complex, it's got to be a Co(II) centre.
Transition state chemistry my beloved
As long as there isnt any yellow in your transiton metal chem im so up for all these colors
Very nice video! I wonder about several points though: 1) what gas is produced after you added hydrogen peroxide? 2) what gas is produced when you are adding extra carbonate salt? 3) Doesn't ammonia carbonate decompose when heated, or in solution this doesn't work like that?
Thank you!
Awesome man!
One thing you could do with the cobalt(II) sulfate is show that it is paramagnetic.
7:41 “smoooke on the waaater!”
Making gunpowder with different types of oxidizers, instead of using kno3 use another stronger oxidizer??????
First time seeing Tom do something that doesn't tar up or go yellow.
Very well done! I can't wait to see some BNCP! That is what your after right? I'm currently working on Amino acid light metal Perchlorates.
That's the one! amino acid perchlorates, sounds powerful, best of luck mate!
@@ExtractionsAndIre Thank you, be careful this compound is a beast!
Keep up the good work
For gods sake, will some glassware company please sponsor this guy?!
Oh ammonia, you devil. The demon chemical and I finally clashed in my chemistry class, and I must agree with your sentiment against it.
Sweet! Next video can be about transition (yellow) metal chemistry! Yay.
no
Extractions&Ire come on it’s what we want to see
@@mercury6800 Real chemists ONLY do yellow chemistry... At least that's what I learned in the states.
Lol when you opened the freezer to show it cooling down I immediately started thinking about pickled beets. Mmm
Great video
I love that he uses a broken grad cylinder
I haven't seen you in a while. Is this your second channel?
this is the second channel! I tried to post here every two weeks, where as the main channel gets and upload every Mars retrograde
@@ExtractionsAndIre You're my favorite meth cook. Loves and kisses my dude.
Well done.
I loved it (as always)! I believe I remember you saying that you dispose of your waste at a professional waste disposal facility. How much does that cost?
I must have said that I intend to one day.... I keep all the transition metal waste segregated, and one day ill drop it all off. But never done it yet!
@@ExtractionsAndIre If you ever do, let us know how it goes! Also, how much of your chemistry do you do illegally? I always want to do more home chemistry, but I am concerned about unintentionally breaking laws. Not trying to have the ATF throw me in jail for the next 20 years.
@@jogandsp just have a tannerite dog chilling near your door. And run at the sound of explosions
6:50 forbidden grape juice
did you have hexahydrate though? You said at around 1:00 that Co is surrounded by 6 H2O, but judging by the color it's probably not hexahydrate?
Is the carbonate technically a chelate type formation? I.e. claw. Something like EDTA, occupying to lig and positions? PS love your work… Is it possible to do a one-off page on payment? To watch enough, but would love to see you rig it out/have more fun.
i really like your videos :D but you should consider building a fume hood so you can work better and saver. i build mine using a tube ventilator and an acrylic glass box that i self assembled. stay save and have fun mfg hazelChem
Damn it. 40 years later, I finally understand what I was doing in Ch 3a.
I hate to be that guy and really don't want to drive you nuts here bud, but @ 6:00 it says "perxoide". I will admit to making that typo many times.
I also spotted a typo in the description. Like you said, I hate to be that guy, but I feel that he needs to know.
@@BackYardScience2000 IT'S OUR DUTY
PERX :(
this doesn't mean anything, i'm just mad
@@ExtractionsAndIre , no worries man. It happens. Just don't be like me and take down a video for a grammatical error that was mkst likely an auto correct issue. Lol! We still love ya! ;)
What’s that other channel, “all chemistry?” I love channels like this. Any help would be appreciated.
On the PUMP!
YEE CRYSTULZ
When’s breaking bad’s silver fulminate coming?!
nice pentavalent carbon you got there
oh no!
What's the music? I really like it
EDIT: Oh ok they're:
1. "Sams car"
2. "19 Ssnb"
From Aphex Twin. Search for "selected SoundCloud works" or "selected ambient works vol 3"
Thanks, Fedor Golishevskiy!
You said you would put this info in there "In a sec". That was yesterday. ^^
Ah I forgot! Who managed to track them down??
@@ExtractionsAndIre
Fedor Golishevskiy
from the other comment talking about the music. :)
Oh crap. It went from pink to blue. Im pretty sure you are pregnant. Lmao
Mmm bacon carbonate... So there is some connection between B12 with Co @ it's centre and these ligands? I wonder
broken measuring cylinders are the best measuring cylinders...
but for safety... use a burner to round off the edges...
Awesome
Sweet testies a new video.
That's some delicious looking pomegranate juice
You need to make a coordination compound of nickel, Nickel Hydrazine Nitrate (NHN)
I though copper sulphate was blue what am i missing