Metal-Metal bonds and isolobal analogy

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  • เผยแพร่เมื่อ 15 ก.ย. 2024
  • Formula to calculate metal metal bonds in clusters and brief discussion on isolobal analogy.

ความคิดเห็น • 153

  • @shabnamdan7898
    @shabnamdan7898 7 ปีที่แล้ว

    Thank you for posting this video, this will be a great help. Your method of teaching is really great.

  • @RAJPAL-gg2yu
    @RAJPAL-gg2yu 6 ปีที่แล้ว

    thanks sir very useful sorry I started now preparing for June 2018 so now I started watch ur videos very usefull thanks alot😊😊😊

  • @A_chem
    @A_chem 4 ปีที่แล้ว +1

    Super explained 🔥🔥 I wish I get a chance to study organic chemistry 🙄

  • @swatisharma-nt7ws
    @swatisharma-nt7ws 6 ปีที่แล้ว

    Thanks a lot buddy.... ice doing a good cause for d ones who can't go anywhere for coaching due to some circumstances.really thanks

  • @sdeb3333
    @sdeb3333 4 ปีที่แล้ว +1

    In W2(OPh)6 the OPh group is bridging that is why it contributes 3 electrons..but how do we know that it is bridging from the formula?

  • @christinemathew4116
    @christinemathew4116 7 ปีที่แล้ว

    Awesome video Sir...it has so much cleared my concepts.

  • @educationtheonlyweapon5897
    @educationtheonlyweapon5897 6 ปีที่แล้ว

    Excellent sir 👍👍👍your way of explanation is amazing
    Tq 😊

  • @Bittu_Chem
    @Bittu_Chem 6 ปีที่แล้ว

    thank ypu so much sir. i am your regular video viewer.. it helps me lot. 😊👍👌💐

  • @nehapandey4539
    @nehapandey4539 6 ปีที่แล้ว

    your all vedios are very helpful sir thankyou so much

    • @nehapandey4539
      @nehapandey4539 6 ปีที่แล้ว

      sir can u tell me a proper plan to prepare for csir june 2018 exam

  • @anjushakurian8180
    @anjushakurian8180 5 ปีที่แล้ว

    Sir pls make videos on all the important topics of csir.bcz, your lectures are really helpful for understanding of topics clearly

  • @goonjthevoiceinside7574
    @goonjthevoiceinside7574 6 ปีที่แล้ว

    Sir....You r simply amazing...... And ur way of explanation is perfect....

  • @pych23
    @pych23 6 ปีที่แล้ว

    Sir, I just want to clear a doubt.
    Isn't bond order means no. of bonds between metal and not total M-M bond in the cluster? So, in case of W2(OPh) 6 we use 30/2 =15 then 18-15=3 i. e. Bond order is 3 though there are only 2 W so both will give same answer.
    I am having doubts please correct me if I'm wrong.

  • @chemistrywithsrinivassir8522
    @chemistrywithsrinivassir8522 7 ปีที่แล้ว

    Excellent, thank you very much sir

  • @uddalokkar7124
    @uddalokkar7124 6 ปีที่แล้ว +1

    Sir , how to find out B.O. in clusters like [ Re2Cl8] (2-) . It will be of great help Sir

  • @debojyotimukherjee262
    @debojyotimukherjee262 6 ปีที่แล้ว

    Sir you just fab...sir plz keep updating us.

  • @saldias7475
    @saldias7475 7 ปีที่แล้ว

    Sir can u tell me how to know if a particular ligand is acting as a bridging ligand in cluster and how to find the no of bridging ligands

  • @sanjuktamishra7930
    @sanjuktamishra7930 7 ปีที่แล้ว

    Sir how many electrons O2 and S2 contribute in neutral counting of metal clusters ?

  • @gowthammanoharan2640
    @gowthammanoharan2640 6 ปีที่แล้ว

    (16:14) It is Inorganic chemistry by Catherine E.Housecraft sir

  • @ankitaupadhyay3545
    @ankitaupadhyay3545 6 ปีที่แล้ว

    what will be the structure of Mn(2-B3H8)(CO)4? NIDO, CLOSO OR ARCHNO?

  • @jagatjotkaur4551
    @jagatjotkaur4551 6 ปีที่แล้ว

    Sir,how to calculate bond order for (Re2cl8)2-, (Re2Cl6 (P(C2H5)3)2, and (Re2Cl4(P(C2H5)Ph2)4)

  • @dixjain9635
    @dixjain9635 5 ปีที่แล้ว

    Is H is isolobal to CH3???

  • @manjunath.haramagatti5962
    @manjunath.haramagatti5962 6 ปีที่แล้ว

    How to calculate no.of bridge and non bridge carbonyl group in metal cluster?

  • @sachukc
    @sachukc 6 ปีที่แล้ว

    sir how can we find the coordination number of phosphorus in compound (PMo12O40)3-??
    I mean compound -(phosphorus molybdenum 12 0xygen40)3- can you help me sir?

  • @navjottaluja1871
    @navjottaluja1871 6 ปีที่แล้ว

    Hey sir.. will it be sufficient to watch inorganic and physical videos provided by you for june net?

  • @bharathipendli4877
    @bharathipendli4877 6 ปีที่แล้ว

    Is your videos and practicing questions are sufficient for preparing net?

  • @ruchiipant3089
    @ruchiipant3089 6 ปีที่แล้ว

    Thanku Sir...ur videos are awesome...Very helpful...Can you explain difference between isoelectronic and isolobal analogy...???

  • @priyankajalotra2300
    @priyankajalotra2300 6 ปีที่แล้ว

    Sir I have asked you earlier to explain ionic strength.. How to calculate it.. We find it usually in the Csir net in some way or the other.

  • @prakashsaha1449
    @prakashsaha1449 5 ปีที่แล้ว

    How can I calculate number of Terminal CO present in Fe2(CO)9 ?

  • @sautrickchowdhury89
    @sautrickchowdhury89 6 ปีที่แล้ว

    very nice explanation...guess you were talking about Inorganic Chemistry by CATHERINE E. HOUSECROFT AND ALAN G. SHARPE

  • @sadhguru2358
    @sadhguru2358 5 ปีที่แล้ว

    sir please tell how to calculate number of bridged carbonmonoxide ligands in metal carbonyl clusters

  • @Venki_Talks
    @Venki_Talks 5 ปีที่แล้ว

    Can you please explain how to calculate Bond order in Nb6Cl12^2+

  • @sapnabarad2739
    @sapnabarad2739 7 ปีที่แล้ว

    SIR howmany electron that HPO4 contribute in [MO2(HPO4)4]-2

  • @sapnabarad2739
    @sapnabarad2739 7 ปีที่แล้ว

    HELLO sir ...sir how many electron that OR contribute in Mo2(OR)6.. sir pls tell me

  • @yogeshmanitripathi8452
    @yogeshmanitripathi8452 6 ปีที่แล้ว

    is there any video on sigmatropic pericyclic reactions

  • @venkateshtakshak8336
    @venkateshtakshak8336 6 ปีที่แล้ว +1

    I'm south indian student that's why sir don't mind I'm always follow ur topics only sir...

  • @navyakalingapatnam8018
    @navyakalingapatnam8018 6 ปีที่แล้ว

    sir,is there any video about chemical periodicity?

  • @sakshimehta7787
    @sakshimehta7787 7 ปีที่แล้ว

    sir can u please make a video on how much a ligand contribute and secondary in isolobal analogy can we a fragment which has 6 electrons

  • @aasthaaggarwal348
    @aasthaaggarwal348 6 ปีที่แล้ว

    Sir please tell how to calculate bond order in metal halide clusters eg in [Nb6Cl12] 2+

  • @shabnamdan7898
    @shabnamdan7898 6 ปีที่แล้ว

    Sir When there are two transition metals in a cluster than for the value of n we should take contribution of both the metals ?

    • @shabnamdan7898
      @shabnamdan7898 6 ปีที่แล้ว

      Gate chemistry Okay. Thanks.

  • @growpotential9016
    @growpotential9016 6 ปีที่แล้ว

    Sir i like ur videos very much
    I have a question calculate no. Of metal metal bond and bridge ligand in complex Co3(CH)(CO)9 given complex follow 18e rule

  • @bharathipendli4877
    @bharathipendli4877 6 ปีที่แล้ว

    What should I do for getting another 80 marks.

  • @sagar07wagh
    @sagar07wagh 7 ปีที่แล้ว

    Very nice good job sir

  • @kakalidevi2497
    @kakalidevi2497 6 ปีที่แล้ว

    Is there any shortcut method to calculate the no of bridging ligand in metal complex ? It will be very much helpful for me if you solve the question no 25 from December 16 part a.

    • @kakalidevi2497
      @kakalidevi2497 6 ปีที่แล้ว

      Is there any provision to buy the vedio?

  • @sivaramakrishna4249
    @sivaramakrishna4249 6 ปีที่แล้ว

    Sir,how many metal metal bonds in {Mo2(OAC)4},could you explain.

  • @pgboy5149
    @pgboy5149 6 ปีที่แล้ว

    sir ..I tried to calculate..bond order of Re2cl8^-2...the way u tought..it is coming out 6..bt it has M-M &bond order = 4...how sir?

    • @alkasharma4161
      @alkasharma4161 6 ปีที่แล้ว

      Manish Tripathi because it is follow 16 electron if u take 16 electron in place of 18 electron then get 4

  • @finazkhan9382
    @finazkhan9382 6 ปีที่แล้ว

    Styx code? What is it for BnHn

  • @astammandal8824
    @astammandal8824 7 ปีที่แล้ว

    Sir ,can you explain
    me why the bridge chlorine atom contributes 3 electron?

  • @sk-ml6ox
    @sk-ml6ox 6 ปีที่แล้ว

    sir, plz explain , how to calculate bridging co or ligand

  • @aasthasingh9784
    @aasthasingh9784 7 ปีที่แล้ว

    Thanks sir.... Plz upload video on jahn teller distortion

  • @akshpreetkaur6932
    @akshpreetkaur6932 6 ปีที่แล้ว

    sir same formula can be used for nitrido and carbido metal cluster??? but there is error by using this formula for nitrodo metal cluster

  • @ishikajha9355
    @ishikajha9355 7 ปีที่แล้ว

    thanks.it is really helpful.sir plz upload video on orgel diagram nd tanabe sugano diagram.

  • @sunandinipaturi1332
    @sunandinipaturi1332 5 ปีที่แล้ว

    Sir plzz calculate m-m bonds in [W2(oph)9]-3 and how can calculate when metal having a oxidation state .🙏🙏

  • @pragyamaheshwari7718
    @pragyamaheshwari7718 6 ปีที่แล้ว

    Sir how to determine bridgeing ligands

  • @priyankabansal9980
    @priyankabansal9980 7 ปีที่แล้ว +5

    sir pls make a video on 18 electron rule as it has come almost in every gate nd csir queation papers

  • @nehasinghneha3974
    @nehasinghneha3974 6 ปีที่แล้ว

    Thankuu. Nice lecture

  • @sachukc
    @sachukc 6 ปีที่แล้ว

    sir phosphorus nitrogen compounds and sulfur nitrogen compounds structures...can u give one class.it is well described in huheey .any other tricks to remember these structures..

  • @dhikshasharma8960
    @dhikshasharma8960 6 ปีที่แล้ว

    Sir plzzzz answer the question of quantum of 2marks june 2017 .....it is 1d box in between 0,8 interval .....47 of series A ..plzzzzzzz it hardly takes 2 min

  • @kitymaurya3102
    @kitymaurya3102 7 ปีที่แล้ว

    Sir plz provide the electrons contributed by the ligands commonly asked in CSIR NET .....

    • @VaishnaviDevi316
      @VaishnaviDevi316 7 ปีที่แล้ว

      Shriver and Atkins very good book to refer

  • @sk-ml6ox
    @sk-ml6ox 6 ปีที่แล้ว

    how can we know no. of bridging and non bridging co ligand

  • @ChemistryTadkaSachinshukla
    @ChemistryTadkaSachinshukla 6 ปีที่แล้ว

    (Re2cl8)²- how many matel matel bond

  • @sapnabarad2739
    @sapnabarad2739 7 ปีที่แล้ว

    sir OR contribute 3 or 1 electron ,? i m little confused

  • @DrRKKadu
    @DrRKKadu 6 ปีที่แล้ว

    Please solve M-M bond in Re2Cl8)-2 ??
    By applying ur Formula..
    I tried.. But m not getting correct ans

    • @DrRKKadu
      @DrRKKadu 6 ปีที่แล้ว

      Ok sir

  • @X_plore
    @X_plore 7 ปีที่แล้ว

    Sir please make a video on Quantum Chemistry, specifically for perturbation theory.

  • @ParthFunJam
    @ParthFunJam 6 ปีที่แล้ว

    Help me to solve the metal metal bond in [(C5H5)Fe(CO)2]2

  • @indrajitmahto5113
    @indrajitmahto5113 7 ปีที่แล้ว

    You are from which place??

  • @brindhasubramanian7375
    @brindhasubramanian7375 6 ปีที่แล้ว

    sir y we using 18 in formula

  • @SantoshYadav-oh6ff
    @SantoshYadav-oh6ff 6 ปีที่แล้ว

    Sir will u pls make a vedio on association dissociations and interchange of inorganic mechanism

  • @dhikshasharma8960
    @dhikshasharma8960 6 ปีที่แล้ว

    Sir plzzz upload a video on mno rule for deducing skeltal electrons......m not able to get thru it from book .....this is given in every book.......nd i hv an intuition dis tym mno rule will cm.....plz plz plz plz upload before sunday

  • @sivan9219
    @sivan9219 7 ปีที่แล้ว

    Sir, good morning
    Am preparing like which of the complex obey 18 rule... In this question we can't remember the contribution of the ligands... And also in this video metal metal bond also need to know the contribution of ligands.. So pls suggest some important points it will help lot like me.. Thank you sir..

    • @sivan9219
      @sivan9219 7 ปีที่แล้ว

      K sir.. Thank you

  • @RahulGupta-ki1wt
    @RahulGupta-ki1wt 6 ปีที่แล้ว +2

    Sir how many electrons RS group contributes in isolobal analogy. Question number 138 June 2014 B series

    • @chembasicsbysujitkumar3705
      @chembasicsbysujitkumar3705 6 ปีที่แล้ว

      actually it contributes 7 elctrons as = 1+6 = 7 elctrons and so it is isolobal with Mn(CO)5 = 7 + 10 = 17 electrons
      as both of them are deficient with 1 electron

  • @vishalsukhija7393
    @vishalsukhija7393 6 ปีที่แล้ว +3

    How OPh contribute 3e, it only contribute 3 if it is bridging nd if it is terminal den contribute only 1e.
    Am i ryt sir?

    • @jagadeeshmanda2497
      @jagadeeshmanda2497 6 ปีที่แล้ว

      Vishal Sukhija yes sir plz clarifie doubt

    • @vishalsukhija7393
      @vishalsukhija7393 6 ปีที่แล้ว

      jagadeesh manda any lone pair containing ligand present on bridging position with 2 metal always contribute 3e, if metal is three then it will contribute 5e

    • @jagadeeshmanda2497
      @jagadeeshmanda2497 6 ปีที่แล้ว

      Vishal Sukhija yes sir i agree with u

    • @Samikshn24
      @Samikshn24 6 ปีที่แล้ว

      Sir please clarify the doubt....OPh contributes 3 e- only while forming bridges

  • @reshmapatil6659
    @reshmapatil6659 5 ปีที่แล้ว

    Sir ur videos are very helpful n u explain very well but I feel ur voice is not clear n can't see what u write on board so if can work it on ,, other wise excellent

  • @shalukumari8280
    @shalukumari8280 6 ปีที่แล้ว

    sir can u plz explain isopoly n heteropoly acids

  • @piyushpattanaik1829
    @piyushpattanaik1829 5 ปีที่แล้ว

    then tell one simplifying the example of tungsten having 4 in no.s and tell the bond order related to no of metal-metal bond in the cluster.

  • @sudheer2643
    @sudheer2643 7 ปีที่แล้ว

    Sir plz provide some more csir shortcuts for bits

  • @thechemistsclub7471
    @thechemistsclub7471 4 ปีที่แล้ว

    Great sir #thechemistsclub

  • @incredibleminds3322
    @incredibleminds3322 7 ปีที่แล้ว +2

    sir, please upload videos on inner and outer sphere mechanism

  • @nargisjafriofficial
    @nargisjafriofficial 7 ปีที่แล้ว

    Very nice explanation but can u give a list which will tell us the valence electrons different ligands carry...since organic students find difficulty in knowing the no.of electrons ligands carry like in this example OPh ligand

    • @nargisjafriofficial
      @nargisjafriofficial 7 ปีที่แล้ว

      Ok...thank you

    • @chetnahasija9975
      @chetnahasija9975 7 ปีที่แล้ว +2

      Nargis Parvaneh there is a pdf file available online.just type 18 e rule pdf you'll find a list of ligands there.Hope it helps

    • @nargisjafriofficial
      @nargisjafriofficial 7 ปีที่แล้ว

      BK Chetna HASIJA Oh thank you so much

  • @dixjain9635
    @dixjain9635 6 ปีที่แล้ว

    It is applicable to only metallocarbonyl but what we do if we have another metal bond for example V2(O)12....

  • @priyankagupta6575
    @priyankagupta6575 6 ปีที่แล้ว

    Sir can you please a video on bio inorganic chemistry ?

  • @devigag6647
    @devigag6647 5 ปีที่แล้ว

    Tq so much sir... Sir plz tell me the valence electrons for some important ligands... I have my exam on tmrw sir... Replay me pls

  • @nehathakur-yg8sf
    @nehathakur-yg8sf 5 ปีที่แล้ว

    Thanks a lot sir

  • @nivasmane5747
    @nivasmane5747 6 ปีที่แล้ว

    thank you sir

  • @radhikakp2613
    @radhikakp2613 6 ปีที่แล้ว

    sir i want a topic for my project..

  • @bobbalisandhya4861
    @bobbalisandhya4861 4 ปีที่แล้ว

    Plz sir make a concise vedio on reactions of carbohydrates

  • @WOA09
    @WOA09 6 ปีที่แล้ว

    sir can u plz solve question no.124setA june2016

  • @menkavishwakarma3449
    @menkavishwakarma3449 6 ปีที่แล้ว

    Sir (Re(Cl)4(PMe2Ph) 4) + ma metal metal kitne hoga

  • @deeh9260
    @deeh9260 6 ปีที่แล้ว

    Thankyou so much !

  • @rahulbishnoi7948
    @rahulbishnoi7948 7 ปีที่แล้ว

    sir plz give video for quantum chemistry

  • @jinpinh
    @jinpinh 7 ปีที่แล้ว

    Thank u Sir...

  • @priyankagupta6575
    @priyankagupta6575 7 ปีที่แล้ว

    sir what is structure of Me2C2B10H10?

  • @Nanocreator2023
    @Nanocreator2023 7 ปีที่แล้ว

    Please explain Mo(OR)6 M-M Bonds

    • @Nanocreator2023
      @Nanocreator2023 7 ปีที่แล้ว

      Gate chemistry I'm sorry, its Mo2(OR)6

    • @Nanocreator2023
      @Nanocreator2023 7 ปีที่แล้ว

      Gate chemistry sir, please give the calculations.. m not able to get it right

  • @abdevilliers7112
    @abdevilliers7112 7 ปีที่แล้ว +1

    Sir please make a video on How to find bridged, terminal ligands in given compounds

  • @priyapriyu8435
    @priyapriyu8435 6 ปีที่แล้ว

    Very nice

  • @aratrikasahana8252
    @aratrikasahana8252 6 ปีที่แล้ว

    Thanks sir

  • @KaleemKhan-lq6kf
    @KaleemKhan-lq6kf 6 ปีที่แล้ว

    Thanks

  • @sapnabarad2739
    @sapnabarad2739 7 ปีที่แล้ว +2

    sir total M-M bond in Rh6(CO)16 ?

  • @chemistrylover2327
    @chemistrylover2327 7 ปีที่แล้ว

    Sir please upload bio inorganic chemistry

  • @habeebaunnisa9344
    @habeebaunnisa9344 7 ปีที่แล้ว

    sir wi u please dicuss complete inorganic chemistry topics related to csir net

  • @priyankabansal9980
    @priyankabansal9980 7 ปีที่แล้ว

    thankyou sir...!!!