18 Thermodynamics -- Delta G, Delta H, and Delta S

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  • เผยแพร่เมื่อ 26 ม.ค. 2025

ความคิดเห็น • 58

  • @gunawansolo
    @gunawansolo 9 หลายเดือนก่อน +4

    Since I am not an English speaking person, a combination of 0.75 playback speed and subtitle make it a perfect enjoyable lecture. Thank you so much.

    • @ChadsPrep
      @ChadsPrep  9 หลายเดือนก่อน

      You're welcome - Glad you found the optimum solution!

  • @MrStrutxD
    @MrStrutxD 4 ปีที่แล้ว +22

    it's insane how you keep making videos at the same exact time that i need them, and they're SPECIFICALLY what i need. thank you. You're really good at this btw.

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว +2

      You're so welcome! And glad the timing has been perfect for you. Might you need a new video on Nuclear Chemistry in the near future?
      Happy Studying!

    • @MrStrutxD
      @MrStrutxD 4 ปีที่แล้ว +1

      @@ChadsPrep Certainly. It's that and molecular orbitals. Not sure what will be contained in gen chem when it comes to MO compared to ochem which i've passed.
      thanks
      In your electrochem video I appreciated how you made us think of a battery acting as an electrolytic cell during recharge.

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว +1

      I won't get a chance to make a new molecular orbital video in the immediate future, but I do have one already in my old playlist...lesson 9.5 in "Chad's General Chemistry Videos." The basics will be similar to what you probably were presented in ochem but with a special presentation on the MO diagram for diatomic molecules included as well. Best in your studies!

  • @בנימיןליפשיץ-ו5ש
    @בנימיןליפשיץ-ו5ש ปีที่แล้ว +3

    You're saving my Physical Chemistry exam, thank you so much!!

    • @ChadsPrep
      @ChadsPrep  ปีที่แล้ว +1

      You're very welcome! And if you're taking Pchem, then you may prefer my more robust treatment of the subject here: www.chadsprep.com/chads-elementary-physical-chemistry-videos/ 😊

  • @ellinorhjelm3382
    @ellinorhjelm3382 4 ปีที่แล้ว +7

    Thank you SO MUCH for this video! Please keep doing them! This is EXACTLY what ASU students need right now! :')

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว +4

      Awesome Ellinor and you're welcome! I hope to post one for the chapter on Electrochemistry tomorrow as well! Happy Studying!🙂

  • @MusafirHoonYaro
    @MusafirHoonYaro 2 ปีที่แล้ว +1

    Chad - I am trying to wrap my head around something based on what I have grasped from your video which, by the way, is fantastic - I wish I had instructors like you during my college days which was EONS ago. Coming back to my question, let me try and articulate it as clearly as I can. Let's take the case when BOTH DeltaH as well as DeltaS are negative - I think a good example would be adsorption of a gas molecule onto a substrate. In this case, the (T x DeltaS) term is going to be negative. In order to determine DeltaG, we are now subtracting this "negative" quantity (T x DeltaS) from DeltaH and the subtraction will reverse the sign of the product (T x DeltaS). Now, the overall sign of DeltaG will depend on the relative magnitudes of DeltaH and the product (T x DeltaS). Whichever is larger will determine the overall sign of DeltaG. If the magnitude of the two quantities are the same, then DeltaG would be "zero". The only variable that I see which can contribute to DeltaG becoming "zero" is "T" . Would we then conclude, based on this example of Adsorption that the particular "T" value of the gas phase that causes DeltaG to be "zero" is the temperature at which the Adsorption will achieve equilibrium? I realize that DeltaH and DeltaS may also be functions of T but let us neglect the differences caused by their dependence on T for the time being. Sorry for the long message but it would help me immensely to know if I am interpreting your explanation correctly. Thank you very much for your feedback. Also, if I misinterpreted your explanation, please let me know the flaw in my thinking.

  • @SaketRamCoolPolar
    @SaketRamCoolPolar 3 ปีที่แล้ว +3

    Thank you so much! This helped so much with the difference between ΔG° and ΔG. I'm a little confused about Gibbs Free Energy and phase changes. I know that ΔG° is 0 for a phase change at the corresponding temperatures, but why exactly is this the case? Also, is it 0 for all temperatures, or just the melting point/boiling point temperatures?

  • @zoeyluo5947
    @zoeyluo5947 3 ปีที่แล้ว

    I think u just saved my life in my chem final! Bless u sir! U make incredible videos!

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      Glad you found the channel, Zoey Luo - Happy Studying!

  • @amandamorton9646
    @amandamorton9646 4 ปีที่แล้ว +2

    You are a fantastic teacher

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว

      Thank you Amanda! 😃 Glad you found this lesson helpful!

  • @tylersorenson3144
    @tylersorenson3144 2 ปีที่แล้ว

    you deserve so many more subscribers this is awesome

    • @ChadsPrep
      @ChadsPrep  2 ปีที่แล้ว

      Thanks, Tyler - Glad you find the channel useful!

  • @JossinJax
    @JossinJax ปีที่แล้ว

    Might not be the best forum for this particular question, but If the universe is expanding, how is there a finite amount of energy in it? Is it using energy to expand? How does the expansion affect the current state?

    • @ChadsPrep
      @ChadsPrep  ปีที่แล้ว

      It isn't 'using' energy so much as transferring energy between different forms - this is the Law of Conservation of Energy. All of these transfers are occuring in the balance of time, space, matter and energy that we have in the universe... it would be a good topic to research if you are interested!

  • @Diogo59123
    @Diogo59123 3 ปีที่แล้ว

    Very nice content, thanks from a Brazilian student of Bioprocess and Biotechnology Engineering

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว +1

      Thanks for watching, Diogo - Happy Studying!

  • @ambersadaqat64
    @ambersadaqat64 4 ปีที่แล้ว +1

    You are a life saver!! Could you do a Physics(1&2) in plain English next?

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว +1

      I do plan to redo the physics 1 and 2 lectures (in plain English) but I'll be working on finishing up these series and some final exam reviews for gen chem and ochem first. Then it's a new biochem series, so it will probably be the Fall semester before I get to the Physics lectures at the earliest. Happy Studying!

  • @strugglingcollegestudent
    @strugglingcollegestudent ปีที่แล้ว

    Chad can you make a more advanced video on this (for physical chemistry)? I am currently in physical chemistry 1 (thermodynamics and kinetics) and my first exam is on Monday

    • @ChadsPrep
      @ChadsPrep  ปีที่แล้ว

      www.chadsprep.com/chads-elementary-physical-chemistry-videos/
      Good news! I have a free set of videos for a physical chemistry thermodynamics course, just not on youtube. But they are back on my site at the above link. Much more comprehensive as Chapter 3 is on Enthalpy, Chapter 4 on Entropy, and Chapter 5 on Gibbs Free Energy. But I think it is just what you're looking for. Happy Studying!

  • @RinaNewhouse
    @RinaNewhouse 3 ปีที่แล้ว

    Chad!! Me again! I’m back rewatching your videos to help prepare me for my quiz today and exam tomorrow!! #summerthingz 😊 LOVE your content.

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      Glad the channel is helpful, Rina - your diligence should pay off!

    • @RinaNewhouse
      @RinaNewhouse 3 ปีที่แล้ว

      @@ChadsPrep Thank you so much! Question: at the 39:00 minute mark, you state that you can find |Delta H| by setting it equal to |-TDeltaS|. Why does that work? And what does that tell us? Thanks!

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      @@RinaNewhouse So this is based on the equation: DG = DH - TDS
      If Delta G is negative a reaction is spontaneous, and if Delta G is positive the reaction is nonspontaneous. For reactions in which Delta H and Delta S are either both positive or both negative there is a temperature dependence for spontaneity. Setting Delta G equal to zero allows us to determine that threshold temperature.
      0 = DH - TDS
      DH = TDS
      And then solving for temperature:
      T = DH/DS
      And this would be the temperature in Kelvin at which the reaction would change from being nonspontaneous to spontaneous (or vice-versa).
      TH-cam comments aren't the best medium for explaining this but hope this helps!

    • @RinaNewhouse
      @RinaNewhouse 3 ปีที่แล้ว

      Another question: at 1:00:00, when Q>K, equilibrium shifts toward the products, and when Q

    • @RinaNewhouse
      @RinaNewhouse 3 ปีที่แล้ว

      And mathematically speaking, how does Delta GK?

  • @Solicanz
    @Solicanz ปีที่แล้ว

    outstanding teacher

  • @elizabethsaldana4052
    @elizabethsaldana4052 4 ปีที่แล้ว +1

    Amazing work! Thank you.

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว

      Thanks Elizabeth and you're welcome!

  • @Fahodinho
    @Fahodinho 4 ปีที่แล้ว +2

    you're a legend

    • @ChadsPrep
      @ChadsPrep  4 ปีที่แล้ว

      Thanks, Fahad!

  • @Ashley-kl9vj
    @Ashley-kl9vj 3 ปีที่แล้ว

    Your website isnt working today :( normally i watch on there but i came here since it wasnt working...
    Anyway thank you so much for these videos, you helped me get the highest grade in my class on my last chem exam

  • @nickyyy01
    @nickyyy01 3 ปีที่แล้ว

    You're literally the best thank you so much!

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      Thank you, Nicky!

  • @blacksakura8515
    @blacksakura8515 3 ปีที่แล้ว

    Is there example of questions that already been solved and explained? You helping me alot. Thank you 😊 💓

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      Hey Black Sakura! Great to hear that you found this helpful, what course are you looking for practice questions on?

  • @RohitRaj-ve7ly
    @RohitRaj-ve7ly 3 ปีที่แล้ว

    Like a true teacher

  • @Chemcrown
    @Chemcrown 3 ปีที่แล้ว

    really enjoying your videos sir, lots of love from Pakistan

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว +1

      Thanks and welcome, chem crown, from U.S.

  • @anneowens2562
    @anneowens2562 3 ปีที่แล้ว

    Great videos! Thank you!

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      Glad you like them, Anne - thanks for saying so!

  • @alessandrac1940
    @alessandrac1940 9 หลายเดือนก่อน

    21:27 try saying "wingardium leviosa!" And see what happens to the marker then 😉

    • @ChadsPrep
      @ChadsPrep  9 หลายเดือนก่อน

  • @bhanupratapchourasia9794
    @bhanupratapchourasia9794 3 ปีที่แล้ว

    Nice video sir 👌

  • @bless6533
    @bless6533 3 ปีที่แล้ว +1

    literally wish that you were my professor

    • @ChadsPrep
      @ChadsPrep  3 ปีที่แล้ว

      Thanks, bb girl!