Nef Reaction & Modifications for CSIR NET,GATE

In this video I have explained the detailed mechanism of NEF Reaction along with various modifications like Mcmurry modification. At time 15.03 I forgot to put + charge on oxygen atom, plz consider + charge. Reaction is of uttermost importance in organic synthesis and equally important for CSIR NET and GATE examination.

[@chemphil1532]

Thanks of wonderful explanation sir.

[@aryansonu2440]

Grt sir plz keep making such videos

[@TETRAHEDRONCHEMISTRYCLASSES]

Sure, I will cover most important topics of organic and inorganic chemistry for CSIR NET December 2019... Stay tuned with TETRAHEDRON CHEMISTRY CLASSES

[@aryansonu2440]

Sure sir

[@sakshiuppal1116]

You said u will tell in end why nef rxn dont work for triple bond, u didn't explain it?? Can you please explain it??

[@jamesfox6201]

in McMurry modification the reaction procced via oxime intermediate followed by imine intermediate to the product carbonyl......please show how the imine intermediate is forming from the oxime

[@TETRAHEDRONCHEMISTRYCLASSES]

Will solve a problem on this when time permits. Thank you😊😊😊

[@shankhajitmondal183]

In McMurry modification OTiCl3 departs. But N should already have a positive charge that U missed,so after expulsion of OTiCl3 N will get 2+.. Thats not possible. Plz go through the original paper by McMurry (1973)..they have clearly mentioned that mechanism is quite uncertain & they couldn’t give authentic arrowpushing in NO formation...Thank U

[@TETRAHEDRONCHEMISTRYCLASSES]

Indeed mechanism is not certain for McMurray modification, I used short method and later I realized this is not good, I went through McMurray original research paper, thanks for pointing out, If you want clear mechanism plz provide your email id or whatsapp number, I will provide you the details.

[@shankhajitmondal183]

@@TETRAHEDRONCHEMISTRYCLASSES my email: [e-mail]
Plz send the detailed step by step mechanism with proper arrowpushing,Thank U in advance

[@aimerschemistry5388]

Sir when a nitro compound having a carbonyl group treated with TiCl3 is there any possibility to undergo MC murry condunsation.

[@TETRAHEDRONCHEMISTRYCLASSES]

To get McMurry product presence of reducing agent is must, if you add little reducing agent you may have alkene.

[@vk4471]

Nice explanation.

[@HJWSM]

pls exlain again the question at 26.20 min

[@TETRAHEDRONCHEMISTRYCLASSES]

In the next video, I will explain.

[@4sacademy487]

@@TETRAHEDRONCHEMISTRYCLASSES ok sir