Wade Rule and Wade-Mingo's rule[Simplest Explanation] | Finding Geometry of Metal Cluster

THIS IS ONE OF THE VERY IMPORTANT VIDEO
In this Video I have discussed Wade Rule and Wade Mingos rule in simplest way;
After watching this video you will be able to assign Closo, Nido, Arachno, to given complex alongwith geometry of the cluster.

[@pritishbiswas7665]

Please give the link of the paper related to [Re(H)9]2-

[@chemistyfacts]

What does eta denotes please calrifies please i got stuck in it

[@neha_AG_Shorts]

Amazing video sir..keep making videos for NET and GATE.

[@amodkumar2712]

As per your taught if normal boranes then we should apply formula as T.v.e- 2n divided by 2 then we get SE pairs which tells geometry but in case of B5H9 it not follow it is square planer why? Kindly regards me! But we get 7 SE pairs it corresponds to pentagonal bipyrmidal but answer is square pyramidal why ? kindly sir! Regards as soon as

[@isha9560]

Thank you very much for making it this simple.
Keep up the good work sir ☺

[@AllBoutChemistry]

isha9560, thanks for the appreciation 😊😊

[@vishwajeet1211]

I have doubt in geometry, for SE Pairs , number of vertices is less than one
eg SEP= 4, number of vertices are 3 and geometry is triangular
Please explain

[@subhasisdey9768]

[Rh6C(CO)15]2- structure is trigonal prism.. Not what you mentioned tricapped trigonal prism.. And you said that CSIR is mistakenly did this.. No.. It's actual answer is given.. Geometry calculation from SEP-1 is not right.. It don't obey for all the cases.. We have to figure it out from TVE count

[@MrVasantakusumakar]

Good explanation

[@yogitapurohit9958]

Sir please make video on electroneutrality principal

[@amodkumar2712]

Sorry sir square pyramidal

[@pg-trb-chemneetcsirchem5282]

Thank you so much sir.if you see this comment please upload some questions for practice at least 2or3 questions.once again thank you

[@ankitasingh4195]

Thanks for this video

[@aryansonu2440]

Osm sir
...I only watch ur videos to clear my doubts....keep uploading more videos.... thanks sir

[@shailaja2009]

Superb explanation. You made me to solve many questions. Thanks a lot

[@anniethakur5595]

19:34 no.of Skeletal electron pairs that come out using formula correspond to the geometry written. On solving [Rh6 (CO)16] SEP= 7 means pentagonal bipyramidal. ?? But it is Octahedron.

[@aakankshasehgal3501]

Really amazing sir... seriously i haven't find such material any where neither in books nor on Internet. I am glad i watched this. Thankyou so much sir. I will share it as much as i can.

[@amodkumar2712]

Sir I mean for 7 it is also square pyramidal geometry adopt

[@zahoorsofi186]

Really fabulous getting short of adjectives.

[@AllBoutChemistry]

thank you

[@shyamsharantripathi4187]

Please apply Wade rule on (Bi3)2- and give it's structure

[@AllBoutChemistry]

shyam sharan Tripathi, I think the question wi not contain 2-, it could be 3- or 1- bcoz with 2- we will get odd electrons and wade rule will not apply there. If you're trying to ask question from CSIR June 2017,then it was Bi³+ there

[@chanderpreet]

Can u plz solve ds C2 B2 H12- its structure closo. Nido. Arachno or hypho... Ds question came in dec 2014 csir

[@chemphile5]

Sb4-2 is example for closo

[@pratibhagade6516]

[ReH8]2- in second question

[@manjeshwariachari111]

Sn92- i got Nido ..but skeletal electrons i got 11 pairs ...means- Oct docodecahedran???
Pls rply sir

[@shubhamkale7474]

Very very Thanku so much sir.
My request to you is
Please make videos on most important formulas of physical chemistry for csir net, gate exams.

[@AllBoutChemistry]

Alright 👍

[@ajitdeshmukh1100]

In question 1) C2=(BH)2; B3H5+(BH)2=B5H7 means 5+7=12 Same do in other examples it will come right. U r teaching very good I like it.

[@manjeshwariachari111]

Sir....i was going through zintl ionS....there was 2 category...lower series ..that u taught in the video...there was higher series also....i.e 4n+0=monocapped, 4n-2 bicapped....it goes. Till 4n-10=hexacapped...
Ex...Bi3Cr2(CO)6-3
Pls rply...it is important...or study only lower series

[@soujanyabanerjee]

For [Rh C (CO)6]2-, you have not subtracted 2 for the C atom in the last step.. if we do that then the skeletal electron pair comes as 8..

[@junmonikhanikar7596]

Mam,can you explain why 2 have to substracted

[@manjeshwariachari111]

Negative charge means ..addition...

[@deeptisaxena3881]

But u described very well

[@kunarapurameshkunarapurame6557]

Superrr sirrr. Thank u soo much sirr. We want more physical chemistry important topics in too easy methods

[@AllBoutChemistry]

videos are already there, please check them :)

[@susmiraja]

Thank you so much sir..

[@pksir888]

Please sir video banate rahna

[@Alwayswonder103]

Is this videos enough to cover topics in organometallic expect rxn mechanicm of organometallics??

[@vishalekal7286]

Very nice sir, thanks

[@gollavineetha3482]

In isolobal ability from metal clusters how 14 electrons isolobal with 4 didn't got

[@VeeraJyothi_-]

Thank you so much sir

[@sathya1289]

Thanku so much sir for making this video 🥳🥳very clr👍

[@haribaskarabbiranantham1308]

sir, easy to understand and revising is made easy by your videos.

[@simarneetkaur2320]

Thanku so much sir.. Keep helping us

[@AllBoutChemistry]

Simarneet Kaur, you're welcome. Keep following the videos

[@solomon_3748]

Sir how to find SEP for [Rh6C(CO)15]2- complex..it contains both transition metal as well as non transition..what would be the geometry and cluster structure? Plz reply sir!

[@deeptisaxena3881]

U can solve all these questions on plane paper, please actually too massive here

[@rohitkr7637]

Thank you sir

[@renukakrishnappa2417]

Thank u

[@mahimahiwal1263]

So nice sir you solved all my problems thanks alottt sir

[@AllBoutChemistry]

You're welcome. 😊
Please subscribe the channel and share with your friends too... 😊😊

[@pksir888]

Sjort trick v batao

[@aravindr9615]

sir can you please tell us how to calculate number of multiple metal-metal bond in Fe3O4 and Cr2(CH3COO)4

[@prajithunathil9381]

Sir
Geometry is based on no.of skeletal electron pair or no.of vertices..pls help

[@chanderpreet]

Really too gd.... Thnks a lot....

[@vandnakushwaha7938]

Thanks sir😊

[@neha_AG_Shorts]

Amazing video sir..pls keep making videos four NET and GATE..

[@gollavineetha3482]

physical chemistry part is very useful for CSIR I request more lectures

[@AllBoutChemistry]

Alright.. I'll try to make more

[@kashminaakhtar4405]

I m really thankful to you sir

[@AllBoutChemistry]

kashmina akhtar, you're welcome 😇
Plz subscribe the channel and share with your friends

[@celineblaze3921]

kashmina akhtar .

[@anjipinneboina6484]

Tq so much

[@arathianoop8722]

Excellent..

[@neha_AG_Shorts]

Amazing video sir..pls keep making videos four NET and GATE..

[@jyotibhatt8117]

And plz solve 88 question of december 2016

[@rajeswariketha9313]

Super sir

[@asl_chemistry]

There is one wrong answer make it correctly 😂

[@shuchitiwari1940]

plz tell Re is one not participate, what about remaining

[@aravindr9615]

how to calculate number of bridging carbonyls in Cp2Fe2(CO)4

[@vipulpatel5249]

where is the links that you mentioned in right corner?

[@harshitagupta6239]

Sir can u solve cluster type for (B10H13(Au(Pph3)))

[@1992shivani1]

At 29:27 in Mn ques there is B3H6.....so total is B4H8 not B4H10

[@AllBoutChemistry]

that is B3H8 only, maybe bcoz of my handwriting it is appearing as B3H6,

[@mahimahiwal1263]

Plse make more video on organometallics imp topics

[@AllBoutChemistry]

I'll try to make... Till then You can also watch other videos on Organometallics uploaded by me...

[@mahimahiwal1263]

Thanku sir

[@pgnandi3878]

Thank you very much sir

[@AllBoutChemistry]

you're welcome :)

[@mr.e.varadharajanlabassist8366]

Thank you so much sir. ur explanation very useful me

[@pankajjangid3983]

okk sir

[@sonukanwar4039]

thnku so much sir for this ....👌👌👌

[@deepikamks]

Wat an explanation sir ji

[@chitra_sen]

Thank you sir....

[@chemysteryassets]

Sir where is the link of [Reh9]2- of ACS publication

[@AllBoutChemistry]

pubs.acs.org/doi/abs/10.1021/jp412003s

[@chemicalscience1808]

really Very good work

[@AllBoutChemistry]

thank you :)

[@pritismita7585]

Thank u sir

[@AllBoutChemistry]

You're welcome 😇

[@srkchemistrypoint3407]

Thank you sir

[@AllBoutChemistry]

You're welcome 😇

[@chemistrystudypoint9190]

Thank you so much sir

[@maryamdaneen7190]

Thank you🙂

[@jyotibhatt8117]

Sir how to know that rhenium is exceptional case in ReH9 type question

[@AllBoutChemistry]

some exception you should know, it will come by reading books

[@jyotibhatt8117]

OK sir and which book

[@kunarapurameshkunarapurame6557]

Physical chemistry csir important topics in easy methods sirr

[@AllBoutChemistry]

I've already uploaded, plz watch my other videos

[@chemistryultra5843]

17.17 sec ka 22= 4×5+2 closo kyo ny hua sir
4×4+2 =22. Archna hi kyo hoga

[@AllBoutChemistry]

n= number of phosphorus here, since we have 5 that's why 4×5+2=22

[@chemistryultra5843]

@@AllBoutChemistry thank u sir I understand..

[@chirrachinna4852]

Thank you Sir

[@ramisettysrinu3318]

Thank you sir

[@anjubisht3124]

Good work

[@kabilans1212]

great explain really good

[@AllBoutChemistry]

Thank you 😊
Plz subscribe and share with your friends

[@kabilans1212]

Definitely

[@kabilans1212]

Iam government Teacher. I like ur videos. Pl dont stop ur videos i will prepare For csir exam

[@zahoorsofi186]

Fabulous great work !

[@AllBoutChemistry]

thank you

[@pankajjangid3983]

what is the geometry of Me2C2B10H10

[@AllBoutChemistry]

This question is from GATE exam and I think I've already solved it, you can check in my GATE 2017 Playlist.

[@chemistyfacts]

@@AllBoutChemistry answer bta dete to kya ho jata sir jiii ye acche teacher ki Nisani nhii h

[@sadanandyadav7555]

very good video sir thanks

[@tayumnime88]

Waoo..superb..Sir

[@mayapandey5268]

Can u please solve qus no 74 of Dec 2017 set B

[@AllBoutChemistry]

i think the answer should be option 2 (one and two)

[@mayapandey5268]

But sir for LS d6 spin will be zero.how there will be e transfer..This will b spin forbidden

[@AllBoutChemistry]

if you see tunabe sugano diagram for LS d6 configuration there it is clearly written that there willbe two spin allowed transitions. check james E huhyee for this.
one more request, i think you have'nt subscribed the channel bcoz your replies are kept in "held for review" section, if so then i request you to subscribe it so that i can get notified when you comment.

[@umendrakhokhar7114]

nice as usual dear bro

[@AllBoutChemistry]

umendra khokhar,
Thank you so much brother 😊

[@gopalkrishnaniyogi5941]

Plz make a video on reductive elimination reaction sir.

[@AllBoutChemistry]

yes sure...

[@josechemistryintamil11than53]

Is this portion for pgt trb also sir

[@AllBoutChemistry]

If it is there in your syllabus, then YES

[@selvit6994]

Write clearly and bigger size,

[@guruprasadsawant4541]

Thanks nice video

[@AllBoutChemistry]

😊