All About Magnesium Oxide Cements

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  • เผยแพร่เมื่อ 22 ธ.ค. 2024

ความคิดเห็น • 351

  • @clintongryke6887
    @clintongryke6887 4 ปีที่แล้ว +17

    This is one of your best and most informative (and highly inspirational) videos.

  • @N0body247
    @N0body247 4 ปีที่แล้ว +15

    This kind of content is why i am subbed. as a kid i hated science, as an adult i love science.. i realize the teacher who bored me... was the problem. You have a way to keep my attention and im learning a ton. Keep going.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +4

      cheers mate - glad you like the channel

    • @Barskor1
      @Barskor1 4 ปีที่แล้ว +3

      Public education is not about education it is about babysitting so your parents can work to pay taxes and making the government your parent.

    • @roberttrimmier3276
      @roberttrimmier3276 6 หลายเดือนก่อน

      ​@Barskor1, while there is something to what you are saying, which also is related to American not having any maternity or paternity leave. I don't babysit anyone. I am a high school science teacher. I teach Earth and Space Science. This year, I am going to teach Environmental Science as well. My pull-out Special Education class is going to learn this content as part of studying Man's impact on the environment. This is fairly technical information and will part of studying the chemistry involved in Environmental Science. I don't babysit anyone, not even the Special Education students. If you walk into my classroom you have to work to earn a passing grade.

  • @michaeltucker8645
    @michaeltucker8645 4 ปีที่แล้ว +9

    I'm signing up for the paid for videos I've self taught myself more in the last 5 years on researching and experimenting myself. Than I ever learned at schools and just recently found your channel around 6 months ago. I have to say you dumb down the process to an understandable level that is such a pleasure to listen to on top on actually preforming these explanations and experiments. I wish I had a science/chemistry teacher such as yourself in school I might have been more attentive instead of so bored about it all. Credit to Dr Young my chemistry tho he was far ahead on most other at the school.

  • @Doncious
    @Doncious 4 ปีที่แล้ว +3

    RMS I have been following your channel now since at least 2014 and I am fascinated by the range of materials and ideas your explore, thanks for all that you share!

  • @beholderer
    @beholderer ปีที่แล้ว +7

    Hi, Robert.
    Does the last mix (Fumed Silica with Magnesium Oxide) is 100% waterproof? Does is resist leaching?

  • @sandrinakeffufal6008
    @sandrinakeffufal6008 หลายเดือนก่อน

    Thank you for explaining this in a practical way, I came here through some other videos which were high on buzzwords and low on detailed explanations. I appreciate it 👍

  • @infinitelyuniversal2390
    @infinitelyuniversal2390 4 ปีที่แล้ว +12

    Very cool, ive been working with Aluminum oxide (do to extreme hardness) and sodium silica, makes really hard cement stone like material but takes weeks to fully set.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +7

      to be honest mate so does Portland cement - we are used to it turning quickly but to really set you have to keep it damp for about 2 weeks to properly cure

    • @infinitelyuniversal2390
      @infinitelyuniversal2390 4 ปีที่แล้ว +4

      @@ThinkingandTinkering really cool! i had no idea i was just playing with ideas* Thanks for Wisdom

  • @shohagpaul2491
    @shohagpaul2491 ปีที่แล้ว +1

    I am from Bangladesh. Recently I'm working on Magnesium Oxychloride cement as part of my MSc thesis. Unfortunately, I'm facing some problems while using MgO powder, MgCl2 and water. As first step, I made a solution of Magnesium chloride hexahydrate by distilled water where molar ratio was 1:13. Then I mix it with MgO powder of molar ratio 7. But, by mixing this way, I could not make any paste of cement. It remained at powder level. I further increased water upto 18 mole. But no change in the condition. That's why it was not possible for me to give shape by mold. Now, I didn't understand what fault is going on actually. I am mixing as per instruction of paper, but not finding the expected result. (Mass contect was =MgO: MgCl2.6H20: H2O= 50g: 36.23g: 41.78g = 7: 1: 13).
    If you help me telling what is wrong here, and tell the actual mixing ratio. Then it will be very helpful for me.
    Thank you

  • @LennartVanBolderick
    @LennartVanBolderick 2 ปีที่แล้ว +2

    Absolutely amazing. Immediately became a member. If I want some in depth professional advice, how to best reach you? Thank you.

  • @jamesdonnelly8888
    @jamesdonnelly8888 3 ปีที่แล้ว +3

    I absolutely love all your videos, and this is no exception. Now I feel I need to go and find out all the properties of these cements. Lots to learn! If there are formulas which can cast well that would be interesting. I wonder if super plasticiser will work, what accelerants can be used, etc. Just today I received my shipments of super placticiser and calcum chloride, and was casting white portland with the kids, and it's a fabulous medium. The surface detail is insane when casting, and the set time is about an hour with a bit of the calcium chloride, plus it's a lovely white. I'm now thinking that some of these recipes must yield a harder cement though, and the billiard ball thing leads the mind to casting busts with a good fake stone appearance. You are a treasure trove.

  • @ApexHumanity
    @ApexHumanity 2 ปีที่แล้ว +1

    This is excellent! Thanks for providing education on these types of portland cement alternatives.

  • @stevemickler452
    @stevemickler452 4 ปีที่แล้ว +6

    If using magnesium oxide and magnesium chloride; I wonder if these can be made from the brine left over from desalination. I've been thinking about how to build OTEC plants to make the desert areas of the oceans bloom by pumping up deep nutrient rich water to soak up CO2.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      ambitious idea mate - good luck with it

    • @lunacyworks
      @lunacyworks 2 ปีที่แล้ว +2

      A UAE group made one called Magnacrete which used the by products of desalination.

  • @TinyGiantLifeStyle
    @TinyGiantLifeStyle 4 ปีที่แล้ว +3

    Foaming agent for MO cement? There is a company building foamed magnesium cement houses. This makes the cement insulating. What might they be using to foam the cement?
    They mentioned that the first try blew the mix out the mold like a volcano.

    • @Barskor1
      @Barskor1 4 ปีที่แล้ว +1

      Oh what it the company's name? I would love to give them a look.

    • @philipvernejules9926
      @philipvernejules9926 4 ปีที่แล้ว +1

      ......In some cases something as simple as polystyrene beads have been incorporated. I understand a suitable protein covering treatment of the beads was done first.

    • @jonnyde
      @jonnyde 4 ปีที่แล้ว

      I did a Gsearch on "foamed magnesium cement houses" and got www.airkrete.com/ as the top hit. Looks awesome ... even Al Gore used it!

    • @justinw1765
      @justinw1765 4 ปีที่แล้ว +1

      @@philipvernejules9926 Polystyrene isn't particularly environmentally friendly.
      I wonder if one could use kapok fiber? Stuffs almost as insulating as lower quality duck down and only slightly heavier.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      I don't know mate - interesting idea though

  • @brandonlaird6876
    @brandonlaird6876 4 ปีที่แล้ว +2

    This is absolute gold! I love how your videos mix (pun intended) just a TINY bit of numbers as an aside to the IDEAS. Ideas are where creativity sets (pun intended) and you end up with a concrete (... yep) understanding of the principle of the matter. I came here as referred by your Sorel Cement Battery video, but I don't know how/why I missed this one since I'm subscribed and all. Anyway, keep up the good work, and keep your foundation (you thought I was done with puns lol) of enjoyment and exploration of scientific principles.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      lol - it's really the idea that matter mate - well - that's what I think

  • @kerembyl
    @kerembyl 4 ปีที่แล้ว +3

    Hi Robert, many thanks for your effort to make this video. Your demonstrations were very useful but i have a question, do you know how much temperature can silica-magnesium oxide mixture can withstand? Thanks.

  • @nancysmith9487
    @nancysmith9487 4 ปีที่แล้ว +1

    Mr. Rose
    Thank you for sharing, great job

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      Mr Rose?

    • @nancysmith9487
      @nancysmith9487 4 ปีที่แล้ว

      London reel, mr.brian rose
      Talented talk show plus mentor. When get chance maybe listen to one.
      Good job sir...

  • @joshuaobrien6137
    @joshuaobrien6137 ปีที่แล้ว +2

    fascinating stuff! Would like to see you explore roman concrete now that we know the recipe(weirdly easy to make given that we lost the recipe thousands of years ago). Also curious what the properties of these cements are and what would happen if you doped one kind of cement/geopolymer with another(its done with metals to give them different properties and I'm curious if it extends to concretes) or if cement lamination(layering different types of cement) would have any benefit.

  • @poptartthecat4038
    @poptartthecat4038 9 หลายเดือนก่อน

    wonderful video! I came here after watching kiwami japan's seawater knife video, where they extracted different salts and reacted them to make a sorrel cement. I wanted more information on the process and this video is perfect!

  • @dummieall3150
    @dummieall3150 ปีที่แล้ว +2

    150 years ago electric arc furnace liner? That’s why I’m looking into magnesium cement

  • @DeliciousDeBlair
    @DeliciousDeBlair 4 ปีที่แล้ว +4

    Now there is a magnesium/aluminum/silicon glass/vitreous compound being used for both high intensity lasers and ballistic glass type applications [transparent vehicle armor].

  • @jonballard4453
    @jonballard4453 ปีที่แล้ว

    I believe you may have just blown the lid right off of the secret that has eluded me on the method of manufacturing of japanese synthetic whetstones or ceramic sharpening stones. I believe it would only require the addition of some ultra finely screened aluminum oxide. Although I believe the stones in referring to are actually fired to harden them. But thank you and if you know how these stones are actually made plz do share thank you and keep up the great work.

  • @markhonea2461
    @markhonea2461 ปีที่แล้ว

    Just now watched this presentation. I have been considering different mediums for sculpting, or putting into a rough mold and then finishing by hand, and I have a serious interest in these compounds as they are very much in the category of characteristics of material simply perfect for my little ideas.
    Little ideas often are the thought-child of future vast industry. Or perhaps I should say 'thought parent'.

  • @strongholdinc1843
    @strongholdinc1843 2 ปีที่แล้ว +2

    AWESOME VIDEO!! Very helpful and love that you mix them live. QUESTION : Which version is has the highest Water Resistance? Would that be the Silica Water Gel ? Also, which do you think has the best impact resistance? Working on a project. Would love some insight. Also, any other better ones for these 2 things you have found? Water proofing and impact ?

  • @NorthernKitty
    @NorthernKitty 4 ปีที่แล้ว +10

    This makes sense - Magnesium Oxide gives me a concrete stomach (as an antacid) so why not use it to make concrete? 😋 Aside from aiding in the ease of mixing, I imagine adding water to the fumed silica makes it easier to weigh? It's so light it virtually "floats on air", but I imagine adding water would help "weigh it down", and then you just need to subtract the weight of the water you added.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +5

      that is pretty much what I do

    • @Thermostone
      @Thermostone 4 ปีที่แล้ว +1

      @@ThinkingandTinkering Thanks Robert , we make Mgo boards and find it very difficult to work with Mgcl2..
      Will try the silica formulations but its going to cost more...
      Can you suggest whats best to make a Mgo board

  • @randycrowe4978
    @randycrowe4978 4 ปีที่แล้ว +6

    awesome job yet again. from what I understand, the great wall of China used a cement that was pure white and extremely durable. Was it one of these cements? Thank you very much, God bless you and your family.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      may well have been mate - China is the world's greatest producer of magnesium oxide

    • @NorthernKitty
      @NorthernKitty 4 ปีที่แล้ว +9

      Construction varies based on the years it was built, but it looks like during the Ming Dynasty they used a mortar made of glutinous rice flour and slaked lime. It was an exceptionally strong mortar, even surviving earthquakes. (Edit:) Looks like the "secret ingredient" to the strength was the amylopectin from the rice flour. It allowed the mix to compact exceptionally well.

    • @Thermostone
      @Thermostone 4 ปีที่แล้ว

      Yes Randy they used Mgo for binding in between the stones and it still hold good

    • @lunacyworks
      @lunacyworks 2 ปีที่แล้ว +1

      @@ThinkingandTinkering many Dams in china were built using a MO base cement

  • @corresandberg
    @corresandberg 4 ปีที่แล้ว +9

    Awesome stuff. Never heard about this before. But I have followed Dr Joseph Davidowitz work and also watches his yearly videos regarding Geopolymer. I don't understand fully what he is talking about since I am a layman, but I find it so interesting so that I still listen to it. I think there is some parts here that are same and others not. Geopolymer is "stone" and resist water really good, hardens without a lot of heat (no need to water it when drying). Robert, this video was super interesting.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +4

      so glad you liked it mate - cheers

    • @technosaurus3805
      @technosaurus3805 4 ปีที่แล้ว +3

      Magnesium oxide is used in many aircrete formulations too.

    • @jonnyde
      @jonnyde 4 ปีที่แล้ว +1

      @@technosaurus3805 I was wondering it that would work - no you know if those mixtures stand up the elements (rain etc) or do they require a special extra coating to weather proof them ?

    • @technosaurus3805
      @technosaurus3805 4 ปีที่แล้ว +1

      @@jonnyde I've only seen it used encapsulated in walls or with stucco on the outside and plaster on the inside. It has good R-value and sound attenuation characteristics though. Honey-Do-Carpenter's channel does a DIY version using Portland cement and a foaming agent.

  • @DanA-nl5uo
    @DanA-nl5uo 4 ปีที่แล้ว +5

    Robert I can't help but be reminded of the aquion battery which used magnesium oxide and salt water as two of the materials. It just makes me wonder if you can make a sold state battery out of these cements.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +3

      pseudo solid for sure - actual solid - don't know

    • @DanA-nl5uo
      @DanA-nl5uo 4 ปีที่แล้ว +2

      @@ThinkingandTinkering I am willing to bet most wouldn't know or care the difference. If the battery would not leak something toxic in an impact failure and not burst into flames there should be applications that make since.
      We just need to get to a point as a society where we don't demand a single solution to all peoblems.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +3

      @@DanA-nl5uo spot on mate and I agree with you

  • @chrisradford6955
    @chrisradford6955 4 ปีที่แล้ว +2

    Which one of these cement types would make for a good refractory; replacing alumina-based insulating fire-bricks?

  • @nr7000000001
    @nr7000000001 4 ปีที่แล้ว +2

    The big advantage of using these cements, is that you can mix them with organic dirty soil. So you can use the soil on site, so you use material that's already there! Just mix it in in the wet ground, that makes it cheaper and easier. With portland cement you must use very pure washed sand so you can not use what's there already. With portland cement everything has to be bought / transported / removed / supplied.

    • @GriffenNaif
      @GriffenNaif 11 หลายเดือนก่อน +1

      So it would be a good match for Earthen Brick?

    • @nr7000000001
      @nr7000000001 11 หลายเดือนก่อน +1

      @@GriffenNaif I haven't tried, I am no expert. Can only say what a huge advantage that would be to the traditional 'buy everything' method.

    • @GriffenNaif
      @GriffenNaif 10 หลายเดือนก่อน

      @@nr7000000001 agreed less buying

    • @GriffenNaif
      @GriffenNaif 9 หลายเดือนก่อน +1

      @@nr7000000001 I see it being used as airkrete and someone answered below huge advantage that you can use it with dirty soil.. "The big advantage of using these cements, is that you can mix them with organic dirty soil. So you can use the soil on site, so you use material that's already there! Just mix it in in the wet ground, that makes it cheaper and easier. With portland cement you must use very pure washed sand so you can not use what's there already. With portland cement everything has to be bought / transported / removed / supplied."

  • @benthere8051
    @benthere8051 4 ปีที่แล้ว +3

    Thanks, Robert. That is good information.

  • @kde5fan737
    @kde5fan737 4 ปีที่แล้ว +3

    Just to get ahead of anyone thinking the phosphate cement is a good idea for large scale use, it isn't unless we find A LOT more deposits of phosphates/phosphorus. P is the main component of residential waste streams that is actually worth recovering due to the cost & availability of global deposits, and we also usually get the benefit of recovering potassium at the same time.

    • @philipvernejules9926
      @philipvernejules9926 4 ปีที่แล้ว +1

      ......even been concerns for continued availability of sand. China for example produced and used more concrete in a decade than USA did in over a hundred years .

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      I did mention that in the video mate - not the China bit - but the phosphate lock for sure

    • @fearlyenrage
      @fearlyenrage หลายเดือนก่อน

      fact; phosphoracids are way to expensive for the industry.

    • @sandrinakeffufal6008
      @sandrinakeffufal6008 หลายเดือนก่อน

      @@kde5fan737 Phosphate fertilisers are destroying the planet, they kill soil microorganisms and leach into waterways creating algal blooms that kill fish etc, so using them for cement/concrete instead is a great solution in my opinion 🤩

  • @mohyolkbouchra3907
    @mohyolkbouchra3907 4 ปีที่แล้ว +5

    Mr SMITH.😍🙄😚.YOU ARE DIFFERENT ...💆‍♂️👍

  • @clintonlau5826
    @clintonlau5826 10 หลายเดือนก่อน +2

    Rob, is the material conductive or can it be made conductive by mixing in carbon or wood ash something to do that and applied to a current collector foil type plates to use in a battery.

  • @petergambier
    @petergambier 4 ปีที่แล้ว +1

    Extremely interesting stuff thanks Dr Rob, I work with lime putty so your film has led me down some intriguing rabbit holes this morning at 3am.
    I also read about Coade stone, a ceramic stonewear 'stone fired twice' as used in many stately homes and Buckingham palace whose original mix was patented in 1722 by Richard Holt but later the clay recipe was perfected and the firing tweaked by Eleanor Coade in about 1760 where her company ended up being the sole artificial stone manufacturer.
    I also read that when Sorel cement is mixed with the magnesium it's the best kind of barrier for radioactive materials.
    Globally we make about 4 billion tons of concrete every year. 1 ton of cement produces about 3/4 ton of co2. Lime mortar produces 80% less co2.
    Geopolymer concrete uses about 95% fuel ash, sets at room temperature and takes about 24 hours to fully set
    and gives off 75% less co2 than cement.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      very interesting stuff mate especially the code stone - thanks for posting

    • @charlesdickens6706
      @charlesdickens6706 3 ปีที่แล้ว +1

      .....is it cos they factor for lime absorbing co2 during it's decades long setting process .locally here the lime mortar appears to have been a failure in construction back to the war years , chimneys and walls crumbling . I reckon the mortar requires a dry climate to work .

  • @greatbilby
    @greatbilby 2 ปีที่แล้ว +1

    Very informative. I have been looking for info on magnesium Oxide for a project I am working on.

  • @ClownWhisper
    @ClownWhisper 4 ปีที่แล้ว +6

    tell me something Robert is there a stage of setting up where you could make designs in it without crumbling it or does it get more brittle and crumbly is it sets up because this might be a perfect answer for me making stamps for pottery work

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +4

      it will cast and hold detail - yes - very interesting idea mate

  • @pblackcrow
    @pblackcrow 3 ปีที่แล้ว +1

    Robert, what about adding hemp to the last one you did and/or something like a hard epoxy?

  • @sonnyhayes689
    @sonnyhayes689 4 ปีที่แล้ว +4

    Fun stuff Rob... You didn't mention the shrinkage rate, would be good to know should you want to mold this material. I have added milled carbon fiber to many different projects with great results. Adding milled carbon fiber should make these cement mixes mush stronger as well as becoming a conductive solid. What are your thoughts?

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      experimenting with composities like mcf additions is always a good idea. these kinds of sorel cements bond very well to organics and carbon structures. the combinations are vast so experimentation is certanly needed and to my mind a good idea. re shrinkage - again individuals will change this so shrinkage should be measured. easy exercise would be to make a bar of it and measure wet and dry - that will give you shrinkage.

    • @sonnyhayes689
      @sonnyhayes689 4 ปีที่แล้ว +1

      @@ThinkingandTinkering - Thanks Rob... If you are interested I'll keep you informed. Currently working with nano colloidal silver. Plan to fill with 60 micron mfc and a new mined material (forgot the name) which will boil in nitric acid to see if we can change properties also to be added to the above components...maybe a new capacitor.

    • @lunacyworks
      @lunacyworks 2 ปีที่แล้ว +1

      @@sonnyhayes689 Any update on your experiment. Always been interested in nanosilver or nitric silver-based items.

    • @sonnyhayes689
      @sonnyhayes689 2 ปีที่แล้ว +1

      @@lunacyworks Lunacyworks...The material was only slightly conductive. Currently working on adding 30 micron milled carbon fiber to UV cured resin. Results are promising.

  • @icebluscorpion
    @icebluscorpion 2 ปีที่แล้ว +1

    Your channel is clearly underrated, keep it up pal! Cheers. How high of a temperature can handle all those types of cement? Could I build a refractory furnace out of it? Could I also foam it with co2?

  • @olindatime8697
    @olindatime8697 2 ปีที่แล้ว +1

    Thanks for a great video. Is the salts in the cement a corrosion risk if it comes into contact with steel?

  • @electronicscrapper4956
    @electronicscrapper4956 4 ปีที่แล้ว +1

    Thank you so much for the information. I'll have something to play around with this weekend

  • @SkookumChoocher
    @SkookumChoocher 4 ปีที่แล้ว +5

    Great video, as usual, thank you sir :). May I ask you also mention some more mixtures, especially ones that are heat and shock resistant, i. e. would be suitable for repair of the inside fire-resistant layer in old ovens or fireplaces? Thank you and keep up the great work!

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +5

      just have a look on google scholar mate - you will find a ton of recipes

    • @jonballard4453
      @jonballard4453 ปีที่แล้ว +1

      @@ThinkingandTinkering could you name some sources to procure some of these oxides? That would be very helpful. I've been trying to figure out how synthetic Japanese whetstones are manufactured and I think you may have just given me my answer. And interestly enough I just broke my 12000 Grit synthetic Whetstone so I'm thinking since it's already broken I could take the pieces put them into a blender grind them up really really good and then add a bit of magnesium oxide and a bit of magnesium chloride and possibly recast the Whetstone. Thank you

  • @revscott58
    @revscott58 2 ปีที่แล้ว +2

    Hello Robert. How would the mix of magnesium oxide with fumed silica work if you used sodium silicate instead of water? It might create an even harder cement.

  • @SteveEh
    @SteveEh 4 ปีที่แล้ว +4

    Wondering if any of these would work in an aircrete mix?
    ohhh more things to try
    Great video Thanks!!

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      glad you liked it mate - cheers

    • @Barskor1
      @Barskor1 4 ปีที่แล้ว +1

      I had the same idea :)

    • @cedricpod
      @cedricpod 4 ปีที่แล้ว +2

      what kind of aircrete? release of hydrogen or addition of a soap derived foam ? or other ?

    • @tdtrecordsmusic
      @tdtrecordsmusic 4 ปีที่แล้ว +2

      Aircrete !!! yes, that is my mission for this year :)

    • @Buzzhumma
      @Buzzhumma 4 ปีที่แล้ว +2

      99guspuppet for releasy of hydrogen you could probably add some aluminium powder to react with alkaline cement . Havent tried it though !

  • @lukebrown6913
    @lukebrown6913 3 ปีที่แล้ว +1

    What are the properties if you mix mag oxide and water glass with and without powered cat litter?

  • @btryba
    @btryba 4 ปีที่แล้ว +15

    Hi Robert. I've been experimenting (like you recommend, actually doing it) with calcium hydroxide and diatomaceous earth (amorphous silicon dioxide). I believe the reaction is generating calcium metasilicate and water (might be "old" terminology). By adding sodium chloride I noticed it seems to improve it's strength. Is this considered a Sorel cement?
    Also, the zinc oxide and zinc chloride cement. Would it maintain strength under sea water since chloride ions are available so less leaching would occur?

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +11

      what you're doing with the silicates is more geopolymer work - not so much cements. i know this can be a confusing definition to get hold of but basically one is a chemical reaction and the other is a physical interaction. it's unlikely to work well under sea water as the chloride ion ppm is really low so diffusion would still be likely to occur.

    • @Kyle-sg4rm
      @Kyle-sg4rm 4 ปีที่แล้ว +3

      Have you tried Calcium hydroxide with Silicic acid? I'm not sure of availability of this type of Silicic acid (orthosilicic acid?), but I think it's the type which precipitates when adding an acid to Sodium/Potassium silicate. So you could potentially make it yourself.
      Another one worth giving a go, if you haven't already, is slaking Calcium oxide and adding a fat, or oil during the process. Once dried this mix yields a "hydrophobic lime". You may also want to try heating slaked lime or even just a slurry of builders lime with some oil on the stove, as the oil/fat may combine with the lime in a similar way.
      I have made "hydrophobic lime" myself but am not 100% sure how it works. One might think the oil/fat would just saponify (With Calcium hydroxide being a strong base) and not add any water resistance at all and just constantly wash and leech out of the dried cement, concrete, mortar or whatever. But I don't think that's the case, considering the hydrophobic properties of the final material. Water just rolls off it. Maybe have a look into how much oil can be used before it compromises strength, I remember reading about it somewhere online.

    • @mrdovie47
      @mrdovie47 4 ปีที่แล้ว +3

      @@ThinkingandTinkering I hear the Romans used Volcanic ash in their water setting concrete.

    • @technosaurus3805
      @technosaurus3805 4 ปีที่แล้ว +3

      @@mrdovie47 crushed, fired clay bricks/pottery works too. The Romans learned that in Germany where there is no volcanic ash.

    • @petergambier
      @petergambier 4 ปีที่แล้ว +1

      @@ThinkingandTinkering, Vetruvius found that after immersion in sea water for 10 years Roman cement produces plate like objects called phillipsite that bend rather than shatter under stress which is why the Roman sea harbour walls are so strong and long lasting.

  • @saraprice3070
    @saraprice3070 7 หลายเดือนก่อน

    Wonderful video! What would happen if you combined the zinc oxide with the fumed silica? Could that be a strong, stable, economical cement that could withstand water?

  • @Ludifant
    @Ludifant 4 ปีที่แล้ว +2

    Cool, now I am wondering how these perform as aircrete. Because they are white, you could add colorants and in small batches with different colours you could make an interesting effect.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      you certainly could mate and aircrew them would be an awesome idea - probably very good as a refractory too

  • @Thermostone
    @Thermostone 2 ปีที่แล้ว

    Quite interesting to note that Fumed silica and Mgo mix.
    Mgcl2 sure does have advantages and disadvantages ...
    Price as comparing to fumed silica is very cheap but Mgcl2 does absorb much humidity and also can cause rusting of non galvanized screws etc.

  • @Mikey42287
    @Mikey42287 4 ปีที่แล้ว

    Wonderful information. I greatly enjoyed your teachings yet again Robert. You never disappoint. 🎩 Thank you.

  • @PaulPassarelli
    @PaulPassarelli 3 ปีที่แล้ว +1

    "Magnesium Oxy-Chloride" as they call is has been used as a lapidary cement for as long as I can remember. My 1970s era 'rock tumbler' came with a small quantity.

  • @dav1dbone
    @dav1dbone 4 ปีที่แล้ว +5

    Hi Robert, would any of these cements be durable enough as moulds for molten Aluminium?
    Regarding your query in the last video Magnesium Oxide is used to treat horses who suffer from anxiety and nervousness.

    • @Barskor1
      @Barskor1 4 ปีที่แล้ว +3

      A 1,000 kg of panicking animal is a deadly thing.

    • @horizoninabucket
      @horizoninabucket 4 ปีที่แล้ว +2

      Magnesium supplementation can be really effective for humans who suffer the same. It fixed my life.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +3

      I don't know mate = probably yes if dried - but worth a try for sure

    • @Zakardis
      @Zakardis 4 ปีที่แล้ว +2

      85% sand, 10% portland cement, 5% water makes an OK reusable mold for metal casting. I'd think you might get similar results replacing the portland cement in that recipe.

    • @eelcohoogendoorn8044
      @eelcohoogendoorn8044 4 ปีที่แล้ว +3

      Ive experimented with this with some success. Try to avoid material comibinations that form hydrates; the water tends to get out of the crystal at fairly low temperatures. Same for carbonates; depends on the particular carbonate but they might also offgas at molten alu temps.

  • @shamblendavidson8166
    @shamblendavidson8166 6 หลายเดือนก่อน

    Always interesting videos. Very informative. I think this is the method that geoship uses, but they add hemp fibers for strength.

  • @ecsyntric
    @ecsyntric 2 ปีที่แล้ว +1

    how about embed a nichrome wire into MgO cement and make a non conductive hotplate

  • @frankm4736
    @frankm4736 4 ปีที่แล้ว +3

    Excellent work mr. smith!!! I have been doing cement experiments myself!! It’s amazing; people like bill gates with endless cash, time and resources- is tackling sci-fi like solutions in low carbon emitting industries. Why aren’t more people putting an effort in on cements??? With cement being the #1 carbon emitter in the world.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      it is fascinating mate - but folks tend to work on what they see and when something is all around tbh we just stop seeing

  • @gnuddi
    @gnuddi ปีที่แล้ว +1

    I wonder if it's actually silica fume you're using rather than fumed silica since there are several articles out there describing the use of silica fume for cement but almost nothing on cements made with fumed silica.

  • @nickceulemans1500
    @nickceulemans1500 4 ปีที่แล้ว +2

    As an architect I am always looking for improving technology and materials. I came across your channel via an interest in hempcrete... the downside is the lime which is very co2 intensive. Could this new cement work as an improved hempcrete?

    • @charlesdickens6706
      @charlesdickens6706 3 ปีที่แล้ว +1

      ......it's all energy intensive
      .The romans had to collect n strip timber from all over the Mediterranean shores n hinterlands to fire up their cement production.

  • @aaknuu
    @aaknuu 4 ปีที่แล้ว +2

    Could you do a version with a small ratio of graphene and compare the strength difference.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      lol - mate - you must know me well enough by now to know what I am going to say next lol = great idea - give it a go and let me know how you get on

  • @nancysmith9487
    @nancysmith9487 4 ปีที่แล้ว +1

    Thank you for your tutorial... nice painting techniques to mix.
    Cheers

  • @philipvernejules9926
    @philipvernejules9926 4 ปีที่แล้ว +2

    ...........Thanks and I'll try some of the things you've outlined. Some version of the zinc oxide cement was or is used as a temporary filling in dentistry .locally I haven't seen lasting results where lime sand mortar was used in building work. The work being good work but the mortar being a letdown . Perhaps some critical factor was lacking in the formula. Portland cement for mortar was rationed during ww2 and I've seen many structures in recent years that needed to be pulled down. The theory was lime mortar strengthened with time due calcium carbonate crystals formation cos of co2 in atmosphere ..I think co2 conc in atmosphere has to be just right and we've upset the Goldilocks already .

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      nice one ate - I didn't know the zinc oxide formula was still used - that is interesting - cheers

  • @richardblanchard2743
    @richardblanchard2743 ปีที่แล้ว +1

    I have seen some videos that describe how to use an expanding cement product to break rocks. You drill holes into the rock, pour in the cement and after a day or so the cement expands and breaks up the rock. Do you have any idea of the composition of this type of cement?

  • @jamest.5001
    @jamest.5001 4 ปีที่แล้ว +2

    Non Portland cement, what about extreme temperature cement? Something that would see peaks of around 1500° American, (°F ) and could see a bit of water! Anything to handle that environment? I have a boiler project I have been putting off, well not really putting off, it hasn't even got that far yet, haha!

  • @Marcbgping
    @Marcbgping 2 ปีที่แล้ว +1

    A forum about making your own sharpening stones brought me here. Magnesoum oxide cement is the material of 'ceramic' 'japanese' 'synthetic' water stones.
    Turns out the raw materials are super cheap

    • @jonballard4453
      @jonballard4453 ปีที่แล้ว

      Tell me more . What is this forum you speak of. This is exactly what I've been trying to figure out for like 5 years. I want to make my own.

    • @jonballard4453
      @jonballard4453 ปีที่แล้ว

      Tell me more . What is this forum you speak of. This is exactly what I've been trying to figure out for like 5 years. I want to make my own.

  • @philippearson2b-art960
    @philippearson2b-art960 3 ปีที่แล้ว +1

    any idea's regarding high temperature resistance.

  • @fritanke2318
    @fritanke2318 4 ปีที่แล้ว +2

    It is cheap and easy to get hold off. I'm afraid thats not the case where I live. But as usual, great stuff.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      that is a shame mate - quite a lot of these materials are like $10 dollars for 20kg or so in most places

  • @thagrit
    @thagrit 4 ปีที่แล้ว +2

    could you use sodium silicate in the magnesium oxide cement?

  • @beholderer
    @beholderer ปีที่แล้ว

    Hi Robert, I have got a question. If the reaction takes place when water is added, then, should we consider these cements "hydraulic cements"?
    Another question: Wouldn't it be better if you mix the 2 powders first and then add the water? Specially with the last one, the fumed silica with magnesium oxide, as dispersing the fumed silica in the magnesium oxide first will make it more workable once you add the water.
    Thanks, Rob.

  • @jamescunliffe9872
    @jamescunliffe9872 4 ปีที่แล้ว +1

    Potentially it could be a structure and battery and atmospheric electricity gatherer or even solar,depending on the ingredients???

  • @htannberg
    @htannberg 4 ปีที่แล้ว +1

    Excellent video. I wonder if by adding graphene or carbon nano tubes if it would give it some better characteristics.

  • @prototype9000
    @prototype9000 4 ปีที่แล้ว +1

    Addingregular salt will increase the setting time also

  • @tobiassorensen7739
    @tobiassorensen7739 8 หลายเดือนก่อน

    Very informative video, thanks.
    I am a restorer I Denmark and read about a danish artist who went to Paris in 1930 when he returned back he started to make cast in something he called "metal cement" do you have any clue of what that could be ?
    Many regards Tobias

  • @konavader
    @konavader 4 ปีที่แล้ว +4

    Aloha Mr. Smith! Have a good day.

  • @GmanBB
    @GmanBB 4 ปีที่แล้ว +2

    Excellent, Robert. Make videos how to make ceramics with aluminum oxide. It will be really useful.

  • @arielkozak
    @arielkozak 4 ปีที่แล้ว +5

    Would this be good for refractory purposes?. I'm making a metal foundry and I'm looking into making my own fire bricks

  • @mteca5093
    @mteca5093 4 ปีที่แล้ว +3

    Lightweight n strong cements are all the rage ... do you have any ways of making them

  • @tomkelly8827
    @tomkelly8827 4 ปีที่แล้ว +1

    Hearing the word, magnesium, reminds me of the time I saw someone throw a magnesium block into a campfire. It lit up the night like it was day time! Wow did it ever burn really really bright!
    So I wonder if these magnesium cements have good fire ratings like portland cements do?
    From what I have seen here, it looks like portland cement is the best all around material, it is very plentiful and cheap, it is workable, sets in a reasnoable rate of time, has fantastic strength and water resistance, fire proof and can be mixed with room temperature water to make a reaction. Portland is an all around better product for sidewalks and foundations. Just add in some tensile reinforcement and you have a really useful product!

  • @SumFugaziSalt
    @SumFugaziSalt 2 ปีที่แล้ว +1

    Great info, thanks.

  • @keithcookman2918
    @keithcookman2918 4 ปีที่แล้ว +3

    Great imagination shared👍

  • @breno2024
    @breno2024 6 หลายเดือนก่อน +1

    I wonder why the manufacturers of MgO boards chose to go with magnesium chloride over a phosphate. Surely they must have known that the chloride would leach due to moisture. I read that Denmark is spending 300 million US dollars to replace Mgo board used in construction.
    The new MgO boards are using magnesium sulphate, which you have also said is susceptible to moisture. Any idea how they might be overcoming the moisture challenge?

    • @SashaInTheCloud
      @SashaInTheCloud 4 หลายเดือนก่อน

      I am interested in this sulfate modification to MgO board too! I thought that chloride free mag oxy sulfate board did not leach...

    • @breno2024
      @breno2024 4 หลายเดือนก่อน

      @@SashaInTheCloud Don't know for sure, just going by what the video reveals. Good luck with your research. I have come to discover it is a fascinating area of material science with many unusual characters doing home experiments.

  • @rogerc7960
    @rogerc7960 4 ปีที่แล้ว +2

    Normal cement is calcium carbonate di-hydrate crystal, other roast carbonates are possible.

  • @SustainableCraig
    @SustainableCraig 7 หลายเดือนก่อน

    There was a recipe mentioned in the vidoe using mgo, borac acid, and phosphate. Does anybody have measurements for this recipe?
    Also are there recommendations for sourcing the phosphate in the US?

  • @mikehewitt1253
    @mikehewitt1253 8 หลายเดือนก่อน

    What about Aluminium Oxide? Fly Ash, Foundry Ash? Mixing with well graded waste glass for durable concrete?

  • @pixelpatter01
    @pixelpatter01 3 ปีที่แล้ว +1

    Could you link your sources for the zinc oxide and magnesium oxide? I'm surprised at the lack of sources except for vitamin stores.

    • @michaelcorbidge7914
      @michaelcorbidge7914 2 ปีที่แล้ว +1

      Pottery/ceramic craft supply stores . 11 months ago i see .

  • @topaquashop353
    @topaquashop353 2 ปีที่แล้ว +1

    is mgo + silika still good shape in long exposure on water?

  • @cymacymulacra2301
    @cymacymulacra2301 4 ปีที่แล้ว +1

    SiO2 is mentioned as an additive. Cristobalite is the neatest cement I've ever heard of. Maybe that would be of special use here?

    • @nicodesmidt4034
      @nicodesmidt4034 4 ปีที่แล้ว +1

      Cristobalite is carcinogenic, watch out

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      it should work well mate

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      Cristobalite is used in dentistry - and di you know carrots are carcinogenic

    • @cymacymulacra2301
      @cymacymulacra2301 4 ปีที่แล้ว

      @@ThinkingandTinkering So is Tums! On topic here, so are you implying with this vid that the valuable effects of the oxide-chloride scheme go towards the lighter alkaline metals or they can be expected to multiply anywhere in atomic weight within those metals? Seems there's a lot of Cerium that goes to waste in industry - maybe specialty cements are its calling?

  • @mudslinger888
    @mudslinger888 2 ปีที่แล้ว

    Will the Mg cement be useful for lining a foundry, kiln, forge, rocket stove. Or only maybe a pizza oven temp range? Max temp? Durable?

  • @Primer595
    @Primer595 4 ปีที่แล้ว

    Great Video Robert! I wonder if the leaching problem could be mitigated by coating the cement with a waterproof material? I know that the Dutch use an 18kg mix of a polymer (recycled plastic bottles! )to a ton of crushed rock to make weather proofing for sea defences such as the final layer on sea walls. I think it was the Romans who discovered cement that we use today. I believe they used weathered lava or pumice stone. Thanks I learned a lot. I wonder if the coating I am suggesting would use adsorbtion or absorbtion to stick to the surface? I suspect you would know.

  • @stevetobias4890
    @stevetobias4890 4 ปีที่แล้ว

    lol, as soon as you started I was asking myself about magnesium sulfate (Epson Salts) I buy it in 20kg bags from the farm supplies cheaper than I can buy two of the small bags you had. Supermarkets make a huge markup by selling 500 to 600 gram bags. Two 20 kg bags just cost me $29 AUD.
    I wonder if an epoxy like coating will stop the leaching which will change the amount of cement production and therefore carbon emissions.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      and epoxy coating would certainly reduce the leaching to next to nothing - and to be honest I am not in the least bit surprised at the mark up - just goes to show what you can save if you buy smart and mix your own

    • @stevetobias4890
      @stevetobias4890 4 ปีที่แล้ว +1

      @@ThinkingandTinkering better than two hydrogen atoms teaming up with an oxygen atom to leach your cement 😄

  • @mikehewitt1253
    @mikehewitt1253 8 หลายเดือนก่อน

    Hi, would using Water Glass with the MgOxide work? Would it also then be waterproof and not leach or weaken?

  • @kennedy67951
    @kennedy67951 4 ปีที่แล้ว +2

    I can see maybe using this as Calking. Shrinking would be very Minimum. Maybe a Glazing Compound for Glass and or Stain Glass Work. Also, Isn't most of this Photo Sensitive? Thanks for the upload.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      it's uses are even broader than that mate - google it - glad you appreciated the video though - cheers

  • @samerabdulhadi9502
    @samerabdulhadi9502 ปีที่แล้ว +2

    Just to ask
    Is it possible to have mg sulphate with out chloride ?
    Thanks

    • @SashaInTheCloud
      @SashaInTheCloud 4 หลายเดือนก่อน

      Yes, it was developed for structural fireproofing purposes, to avoide the plague of chloride leaching that corroded many buildings made with mag oxy chlor buildings into an expensive nightmare.

  • @edwardcdg
    @edwardcdg 4 ปีที่แล้ว +1

    How does the surface area of diatomaceous earth compare to fumed silica? They are both silica.

    • @justinw1765
      @justinw1765 4 ปีที่แล้ว +1

      It's kind of like comparing powdered sugar to cotton candy--with the latter being like fumed silica--the fluffier and lighter the form, generally the more surface area.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      I have no idea mate

  • @andymiddleton6431
    @andymiddleton6431 4 ปีที่แล้ว +1

    How would hempcrete fit into all this? It is more ecological as it traps more CO2 over time as it hardens, I believe..?

  • @cygnusrays
    @cygnusrays 4 ปีที่แล้ว +1

    Just what I’ve been looking for, thank you! Are you able to tell me would the silica mix be suitable to use to render garden beds (inside and out), or should I stick with the Ammonium Phosphate mix?

  • @binyam8578
    @binyam8578 2 ปีที่แล้ว +1

    Please can I learn from you magnesium oxide and magnesium selft from wher can get? And thes is man made product or natural mine ? please could you tell me can I learn from you

    • @michaelcorbidge7914
      @michaelcorbidge7914 2 ปีที่แล้ว +1

      Magnesium oxide and zinc oxide are available easily from pottery/ceramic craft supply stores .

  • @kathleenjones9207
    @kathleenjones9207 3 ปีที่แล้ว

    Thank you for such a wonderful video. I was wondering if you could add laurel sulfate and air to make fire retardant concrete insulation?

  • @rudolfdesadeleer7995
    @rudolfdesadeleer7995 4 ปีที่แล้ว +1

    if you use zinkoxide and zinksulfate add graphene or graphite you would make the concrete to be hydrophobic?

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +1

      dunno - worth a try - go for it

    • @rudolfdesadeleer7995
      @rudolfdesadeleer7995 4 ปีที่แล้ว +1

      @@ThinkingandTinkering thanks and I will give it a try it with rust...this should be the cheapest rustconverter out there...just put some Iron sulfate on the cleaned rusted surface and .....we have iron cement instead of rust....I will give that a try

    • @GriffenNaif
      @GriffenNaif 9 หลายเดือนก่อน

      @@rudolfdesadeleer7995 how did it go?

  • @deltonlomatai2309
    @deltonlomatai2309 ปีที่แล้ว

    Have you heard about Rosendale cement?

  • @tebbi67
    @tebbi67 4 ปีที่แล้ว +2

    I think that all of us who always look here should get together and nominate him for the Right Livelihood Award.
    Ant THX for this Video.

    • @ThinkingandTinkering
      @ThinkingandTinkering  4 ปีที่แล้ว +2

      lol - cheers mate and thanks for taking the time to say that

  • @garethrobinson1729
    @garethrobinson1729 3 ปีที่แล้ว

    This is so detailed to detailed for me IV been looking for a fire cement for a fire pit could someone please put me in the right direction

    • @C-M-E
      @C-M-E 3 ปีที่แล้ว +1

      I'm actually doing a forge/kiln in the coming days and probably got on this vid due to finding an old refractory brick video from the 50s, which showed how they made magnesium oxide/chloride alumina refractory bricks for furnaces. Personally I've settled on a mix of sand, silica powder, aluminum oxide and a inner wall of silicon carbide for the face coating (as I have all these presently) and plan to use sodium silicate as the binding agent. While the MGo idea seems like it'd work quite well with some high temp additives, getting enough in large quantities--even though the raw materials are stupid cheap--shipped to the house would cost an absolute fortune, so I'm going with my first plan. I also found a 94 page thesis from 1949 on phosphoric acid bonding to refractory materials and am reading through that looking for clues to aid what the kiln project is being built for, UHTC research. So much forgotten knowledge from the 'dark era' of scientific time that you have to really butter up your google-fu to find it these days, which is where I find so much value in Robert's videos in condensing that into usable chunks!

    • @garethrobinson1729
      @garethrobinson1729 3 ปีที่แล้ว

      Looking a strong fireproof mix that will be able to take the weather I'll be watching the kiln for sure thanks