E1 Reaction Mechanism With Alcohol Dehydration & Ring Expansion Problems

แชร์
ฝัง
  • เผยแพร่เมื่อ 29 เม.ย. 2018
  • This organic chemistry video tutorial provides a basic introduction into the E1 reaction mechanism. It includes example problems with carbocation rearrangements such as the hydride shift, methyl shift, and the ring expansion. It discusses E1 elimination reactions of alkyl halides and the E1 dehydration reaction of alcohols using H2SO4.
    Stereochemistry R/S Configuration:
    • Stereochemistry - R S ...
    Optical Activity & Specific Rotation:
    • Optical Activity - Spe...
    SN1, SN2, E1, E2 Reaction Mechanisms:
    • SN2 SN1 E1 E2 Reaction...
    SN2 Reaction Mechanisms:
    • SN2 Reaction Mechanisms
    SN2 - Test Question:
    • SN2 Reaction Mechanism...
    _______________________________
    SN1 Reaction Mechanisms:
    • SN1 Reaction Mechanism
    Carbocation Stability - Hyperconjugation:
    • Carbocation Stability ...
    Carbanion Stability:
    • Carbanion Stability
    Protic Vs Aprotic Solvents:
    • Polar Protic Solvents ...
    E1 Ring Expansion:
    • E1 Reaction Mechanism ...
    E2 - Test Question:
    • Zaitsev vs Hoffman's P...
    ________________________________
    E2 Stereochemistry - Newman Projections:
    • E2 Stereochemistry Wit...
    SN1, SN2, E1, E2 - Practice Test:
    • SN1 SN2 E1 E2 Reaction...
    Organic Chemistry PDF Worksheets:
    www.video-tutor.net/orgo-chem...
    Organic Chemistry 1 Exam 2 Playlist:
    bit.ly/3PKEApB
    Full-Length Videos and Worksheets:
    / collections

ความคิดเห็น • 62

  • @TheOrganicChemistryTutor
    @TheOrganicChemistryTutor  ปีที่แล้ว +2

    Organic Chemistry PDF Worksheets: www.video-tutor.net/orgo-chem.html
    Full-Length Exams and Worksheets: www.patreon.com/MathScienceTutor/collections
    Next Video: th-cam.com/video/_pp9fxe22yc/w-d-xo.html

  • @prettybird865
    @prettybird865 6 ปีที่แล้ว +70

    You're actually the best dude. If I don't understand something about chem, you're the first place I look. Perfect voice for explaining things too!

  • @munch6814
    @munch6814 6 ปีที่แล้ว +11

    Thanks sooo much. It really helped. Please upload more like E1,E2,SN1,SN2, Stereoisomer etc.,plssss

  • @tommyguir3820
    @tommyguir3820 3 ปีที่แล้ว +52

    I watched 6 ads during the course of this video..... youtube is really pushing it

  • @sarahholland5980
    @sarahholland5980 3 ปีที่แล้ว +16

    thank you for going through major/minor products! my professor rushes through it without explaining and I was so confused.

  • @mrmusaa2260
    @mrmusaa2260 ปีที่แล้ว +1

    I was looking for the major and minor products. Surprisingly, I found the hydride and methyl shifts!

  • @SuloveKaushik
    @SuloveKaushik 9 หลายเดือนก่อน +2

    I sometimes think what would happened of a person like me if a tutor like you was never there on TH-cam😢❤❤

  • @omagaomaga6313
    @omagaomaga6313 2 ปีที่แล้ว +1

    This dude is simply good at what he does.

  • @phil1pd
    @phil1pd 2 ปีที่แล้ว +2

    A playlist on migratory rearrangements would be a helpful addition.

  • @randhirkotwal9738
    @randhirkotwal9738 6 ปีที่แล้ว +12

    Sir please upload more videos on organic chemistry

  • @randhirkotwal9738
    @randhirkotwal9738 6 ปีที่แล้ว +18

    We are very thankful for this...

  • @tlili3990
    @tlili3990 2 ปีที่แล้ว

    You're so much better than both of my professors

  • @arditehrani1186
    @arditehrani1186 ปีที่แล้ว +1

    So many thanks for your great simple educational videos!

  • @preetyluli7617
    @preetyluli7617 3 ปีที่แล้ว +1

    Thanks so much🤗🤗
    May God bless you😇😇

  • @tangohdalij2590
    @tangohdalij2590 ปีที่แล้ว

    Very good and understandable video

  • @somgautam-yi4wk
    @somgautam-yi4wk 7 หลายเดือนก่อน

    7:41 i would like to make a correction - although you got the correct majar product but since you made the cabocation you should had also done the hydride shift from left alpha H . by this you would get a more stable carbocation and 2 alkenes..HOPE YOU WILL DO THE CORRECTION

  • @indianchika123
    @indianchika123 5 ปีที่แล้ว +87

    i seriously have a crush on you

    • @walterwhite4699
      @walterwhite4699 3 ปีที่แล้ว +11

      awkward...

    • @Gboy163
      @Gboy163 ปีที่แล้ว

      Ayo 🤔

    • @shaqaman1862
      @shaqaman1862 ปีที่แล้ว +1

      Pause.

    • @inexp1
      @inexp1 9 หลายเดือนก่อน +3

      @@shaqaman1862 feel free to attempt this question

    • @esliaddaccount1
      @esliaddaccount1 8 หลายเดือนก่อน

      Thats like having a crush on ur professor

  • @nostro1940
    @nostro1940 ปีที่แล้ว

    1:00 is the subproduct a H30 (-) ? cause it loses a proton?

  • @sahitiputcha
    @sahitiputcha 5 ปีที่แล้ว +3

    Your voice is awesome......:)

  • @shainablanco4051
    @shainablanco4051 6 ปีที่แล้ว +2

    This is so Helpful hehehe😁

  • @GG-co2tb
    @GG-co2tb 7 หลายเดือนก่อน

    When do you use EtOH vs KOtBu/-OtBu?

  • @talybodzhakow2641
    @talybodzhakow2641 3 ปีที่แล้ว

    Thank you

  • @SophieSong-vf7bz
    @SophieSong-vf7bz 8 หลายเดือนก่อน

    Thank you for the clear explanations! For the last example, can EtOH attack the H on the left side and give the same product?

    • @classicalcole7312
      @classicalcole7312 7 หลายเดือนก่อน

      Yes there is a line of symmetry down the center, so that should give you the same product.

  • @bjswamy3193
    @bjswamy3193 5 ปีที่แล้ว +3

    But isn't dehydrohalogenation E2 reaction? Why is it showing E1 mechanism in the video (for that ring expansion question)

    • @msadjei9147
      @msadjei9147 4 หลายเดือนก่อน

      I think it's because of the solvent, it's not strong enough for E2

  • @camy563
    @camy563 3 ปีที่แล้ว +1

    Thaaaank youuuu!!!!

  • @randhirkotwal9738
    @randhirkotwal9738 6 ปีที่แล้ว +2

    I know this week is busy for you in uploading videos..

  • @zaminahmed297
    @zaminahmed297 3 ปีที่แล้ว +9

    You are great dude. I wish all chem professors were like you. A suggestion I would give though is could you make some of the videos a little shorter?

  • @theresa.gerges
    @theresa.gerges 2 ปีที่แล้ว +2

    what is the difference between E1 and E2 mechanims? Like when do we use E1 and when do we use E2?

    • @xianhezhang3070
      @xianhezhang3070 2 ปีที่แล้ว +1

      Same as Sn1 and Sn2, E1 when steric hinderance is high and E2 when steric hinderance is low.

    • @Future_iitian_
      @Future_iitian_ ปีที่แล้ว

      ​@@xianhezhang3070nooo you are so wrong
      E1 is used when good leaving group and weak base
      E2 is used when bad leaving group and strong base attacking

  • @user-bu6sp7dw8f
    @user-bu6sp7dw8f 2 ปีที่แล้ว +4

    PHARMACY STUDENT IS HERE
    THX

  • @a.i1137
    @a.i1137 2 ปีที่แล้ว +1

    11:52 "basically" make the double bond..... I see what you did there

  • @nikodg194
    @nikodg194 5 ปีที่แล้ว +4

    I bet that hso4- is too weak base to deprotonate anything

  • @chipp255
    @chipp255 8 หลายเดือนก่อน

    9:00 where did that hydrogen come from?

  • @nostro1940
    @nostro1940 ปีที่แล้ว +1

    10:17
    1 carbon missing

  • @akshanshuanand9493
    @akshanshuanand9493 3 ปีที่แล้ว

    How is H2O acting like a weak base here? Shouldn't it donate an electron pair to the carbocation and follow Sn1 instead of E1?

    • @aylora7033
      @aylora7033 2 ปีที่แล้ว

      are u saying because the strong acid reacted with the R-OH which is a weak base and donated a proton that H2O+ is now is a conjugate strong acid? H2O+ left as H2O and became a good stable leaving base. besides, Sn1 wouldnt happen because there is heat involved

    • @Future_iitian_
      @Future_iitian_ ปีที่แล้ว

      H20 is neutral so it's conjugate base is also weak

  • @ngjackie7213
    @ngjackie7213 6 ปีที่แล้ว

    Omg so many vids

  • @shayneomale2776
    @shayneomale2776 ปีที่แล้ว

    Really good, but cant say do this question but then introduce new stuff. Get's quite frustrating.

  • @gitmemed2668
    @gitmemed2668 3 ปีที่แล้ว

    what is the plus icon?

  • @alexitc1724
    @alexitc1724 ปีที่แล้ว

    I love you

  • @alexia7748
    @alexia7748 ปีที่แล้ว

    Hello, why does the leaving group leave?

    • @Moonlight-xl8wh
      @Moonlight-xl8wh ปีที่แล้ว +1

      as in e1 carbon becomes bulky and 3 degree carbocation is stable enough so halogen has to leave

    • @Future_iitian_
      @Future_iitian_ ปีที่แล้ว

      ​@@Moonlight-xl8whkindly don't give false information
      If u don't know just shut up and sit down

    • @Future_iitian_
      @Future_iitian_ ปีที่แล้ว

      Dear Alexia , leaving group leaves because the solvent used is polar protic
      Polar solvents tends to break the bond which are ionic by dipole dipole interactions
      If you have any other doubt you can ask me
      I am from IIT (the institute which you get after giving the toughest exam of world)

    • @TheHolyQuran2212
      @TheHolyQuran2212 4 หลายเดือนก่อน

      ​@@Future_iitian_what's protic I can understand polar but what's polar and non polar protic

    • @Future_iitian_
      @Future_iitian_ 4 หลายเดือนก่อน

      @@TheHolyQuran2212 the solvent which has a proton to share is called protic (H+)