Nitration of Benzene Mechanism - Electrophilic Aromatic Substitution Reactions

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  • เผยแพร่เมื่อ 28 พ.ย. 2024

ความคิดเห็น • 77

  • @TheOrganicChemistryTutor
    @TheOrganicChemistryTutor  10 หลายเดือนก่อน +1

    Final Exams and Video Playlists: www.video-tutor.net/

  • @shahin2324
    @shahin2324 3 ปีที่แล้ว +73

    The next generation of doctors will owe you a lot! Thanks for making these videos!

    • @vejishin
      @vejishin ปีที่แล้ว +4

      what does this has to do with doctor?

    • @maameakosua
      @maameakosua ปีที่แล้ว +1

      The whole science world own him a lot ❤

    • @simonvutov7575
      @simonvutov7575 9 หลายเดือนก่อน +3

      Yes!! And not only doctors, but engineers and scientists too!!

  • @Professor_Gaoboi03
    @Professor_Gaoboi03 ปีที่แล้ว +19

    Good work Sir ...whenever you feel down remember you helped me become a Pharmacist , i started receiving your free tuition since high school , i am doing my second year now and still your videos are very useful. God Bless you 🙏🤝

  • @mohitgoswami1739
    @mohitgoswami1739 2 ปีที่แล้ว +7

    The best nitration reaction in detail i have ever seen.... thank you so much

  • @devyndevyndevyn
    @devyndevyndevyn 8 หลายเดือนก่อน +2

    thank u eight billion times king

  • @QMED-rx9xj
    @QMED-rx9xj 3 ปีที่แล้ว +5

    You saved my educational life 🥺🥺🥺

  • @edwardjarvis3442
    @edwardjarvis3442 4 ปีที่แล้ว +55

    I dont understand chemistry. Why does something form if its going to be unstable and have loads of lone pairs. Why do the lone electrons have to be in pairs. What even makes something stable or unstable.

    • @nexusdavies7502
      @nexusdavies7502 2 ปีที่แล้ว +6

      Something is formed even if it's unstable to proceed the reaction, you can always just not form it and let it be but we have to see other possibilities, also sometimes formation of something unstable leads to something more stable than what we started with.
      Lone electrons are always in pairs because of distribution of electrons in orbitals, I don't clearly remember the name of the rule right now but look up electronic configuration and you'll find the distribution rules.
      Stability depends on a lot of factors, no of alpha carbons, attachment of electron withdrawing group or electron donating group, electronegativity of carbon etc, you'll have to look it up and understand every concept to be clear on this one

    • @manjukukreti5105
      @manjukukreti5105 ปีที่แล้ว +11

      Dude chemistry is like minecraft but its really infinite exploration its a natural phenomenon that we are trying to understand by analysing and giving facts and proof, no one can change it its just as "it is what it is"
      We see this sort of thing in every day life even from the movement you were born you were forced to learn numbers(1,2,3.....) If you were yo say it dont make any sense you will be correct but you still need it to perform mathematical operations , just take imaginary number like who the hell need it but......oof
      I thing you understand what i am trying to convey you here , bye

    • @scareflare7553
      @scareflare7553 ปีที่แล้ว +3

      It's like exactly asking why the matters in the universe work like this and why they are constituted like this. No one knows, humans just study the universe and these are observed facts about the matter in the universe, based on those facts, we then study further their behaviour and properties.

    • @thealchemist01
      @thealchemist01 ปีที่แล้ว +3

      Regarding the stability question:
      You might have often heard that "less energy is more stable". The energy referred here is the Potential Energy.
      Take two positive charges. If we just put them close to each other and let go, what would happen?
      They would repel each other and move far apart, right?
      As they move far apart their potential energy decreases.
      Stability is kind of like Nature's favourite condition. We don't know why it's like that but nature prefers systems that have less energy. So it tends to push things towards a less energy state i.e, stable condition.
      Hope this helps. If you want you can check out Khan Academy video on the same topic "Why less energy means stability"

    • @happy_heart-
      @happy_heart- 11 หลายเดือนก่อน

      Dude this all are fake, bcz how can any sceintist see with his naked eyes whats happening inside the test tube

  • @jesusmrosario-claudio4104
    @jesusmrosario-claudio4104 4 ปีที่แล้ว +5

    Thank you once again.

    • @tom_winguill
      @tom_winguill 4 ปีที่แล้ว +1

      did you kept this comment for every video,
      great!!!🎇🎇

    • @jesusmrosario-claudio4104
      @jesusmrosario-claudio4104 4 ปีที่แล้ว +1

      @@tom_winguill yes sir

    • @tom_winguill
      @tom_winguill 4 ปีที่แล้ว +1

      @@jesusmrosario-claudio4104 did you just cracked any examination because of him??

    • @jesusmrosario-claudio4104
      @jesusmrosario-claudio4104 4 ปีที่แล้ว +1

      @@tom_winguill i must say that thankfully I do.

  • @theak-1663
    @theak-1663 3 ปีที่แล้ว +11

    question, what about para meta directors how do they fit in if the nitro group is a deactivation group?

    • @nagulaneetigna5737
      @nagulaneetigna5737 3 ปีที่แล้ว +2

      Dude did you get the answer..I was thinking the same

  • @alliehunu8475
    @alliehunu8475 9 หลายเดือนก่อน

    Why does the o in the oh group (on nitric acid) grab the hydrogen on sulfuric acid rather than the negative o in nitric acid?

  • @harleyquinnismommy6679
    @harleyquinnismommy6679 2 ปีที่แล้ว

    im just here to listen to that angelic voice ngl

  • @areeshasvlogs4452
    @areeshasvlogs4452 3 หลายเดือนก่อน

    does the location of nitronium ion has any effect on the benzene ring?

  • @RODERICKPETER
    @RODERICKPETER 2 หลายเดือนก่อน

    SORRY SIR, THE NITRATE, CAN YOU EXPLAIN HOW THE POSITIVE SIGN FROM NITROGEN WAS STABILIZED BEFORE NO2 WAS FORM AND ATTACHED TO THE BENZENE RING? MAYBE YOU FORGOT THAT PART, PLEASE EXPLAIN IN YOUR NEXT VIDEO.
    🥰🥰🥰😀

  • @poorani...chemistryr..3822
    @poorani...chemistryr..3822 5 ปีที่แล้ว +2

    Resonance structure of phenol

  • @shirmilwelgama8521
    @shirmilwelgama8521 3 ปีที่แล้ว +1

    many thanks!!!

  • @irtiiii79
    @irtiiii79 22 วันที่ผ่านมา

    how did base take out hydrogen in the last step??

  • @sakshiupadhyay9940
    @sakshiupadhyay9940 5 ปีที่แล้ว +1

    Which is most readily nitrated

  • @senny-
    @senny- 5 หลายเดือนก่อน

    My question is: why sulfuric acid specifically?

  • @school5820
    @school5820 3 ปีที่แล้ว +1

    can this also be applied for a xanthoproteic test?

  • @DAKTROPBOYS2
    @DAKTROPBOYS2 3 ปีที่แล้ว +1

    Thanks sir

  • @negarolfati36
    @negarolfati36 2 ปีที่แล้ว

    It doesn't get rid of carbocation in step 2, but H. Or am I wrong?

  • @kelseybrennan3127
    @kelseybrennan3127 3 ปีที่แล้ว +1

    thank you so much. much luv brutha

  • @pranjaljoshi5661
    @pranjaljoshi5661 4 ปีที่แล้ว +5

    At 4:36 why didnt Base took the other Hydrogen why the one connected with NO2?

    • @tanushreenainawa3192
      @tanushreenainawa3192 4 ปีที่แล้ว +1

      Because that time also electrophile is trying to remove that particular hydrogen so it will become weak as compared to other carbon hydrogen bonds

    • @ilimselyardm9698
      @ilimselyardm9698 3 ปีที่แล้ว +1

      From another point of view
      That NO2 group has -I (it pulls electrons itselfs) so that Hydrogen bond is weakened it will be easier to remove that hydrogen compared to other carbons hydrogen

  • @mekdesbelete8766
    @mekdesbelete8766 3 ปีที่แล้ว +1

    best one deal of thanks

  • @justinli4190
    @justinli4190 3 ปีที่แล้ว +2

    I have a question about the step you did for producing NO2+ (timestamp: 2:50 )
    I saw a different equation.
    HNO3+2H2SO4=NO2+ + H3O+ + 2HSO4-
    This makes more sense to me for some reason, could you check it pls, I don't think water can be one of the bases in this case.

    • @yashkalia2311
      @yashkalia2311 3 ปีที่แล้ว

      Hno3 can be used as base
      I think

  • @vivianonwudiwe8800
    @vivianonwudiwe8800 2 ปีที่แล้ว

    What will be the rate determining step of it? The attack of the double bond from benzene to the nitronium ion in order to create the carbonation ion intermediate?

    • @aut199
      @aut199 2 ปีที่แล้ว +2

      The rate determining step (RDS) is the slowest step in the reaction. Here the RDS is formation of Sigma complex which happens after the generated electrophile attacks the aromatic ring

  • @hubertrichardo4792
    @hubertrichardo4792 2 ปีที่แล้ว

    In my textbook it says no2 withdraws electrons from the benzene ring but isnt it a + ion because it has an extra electron

    • @juicoposting
      @juicoposting 2 ปีที่แล้ว +3

      It doesn't have extra electrons but a positive charge so it wants electrons.

  • @rassimsimou1594
    @rassimsimou1594 6 หลายเดือนก่อน

    Good

  • @senchen3238
    @senchen3238 4 ปีที่แล้ว +2

    I’m still thinking about 4:00 it’s negative charge instead of positive

    • @김창진-c3b
      @김창진-c3b 4 ปีที่แล้ว +2

      you still?
      -two pi electrons are used to make one sigma combine
      so it would be relatively positive

    • @edwardjarvis3442
      @edwardjarvis3442 4 ปีที่แล้ว

      @@김창진-c3b what are pi electrons. What is sigma.

    • @priyanshurautela3581
      @priyanshurautela3581 3 ปีที่แล้ว +1

      @@edwardjarvis3442 pi pi hota h aur sigma sigma hota h

    • @aut199
      @aut199 2 ปีที่แล้ว

      @@edwardjarvis3442 double bond between atoms is called pi bond and single bond is called Sigma bond.

  • @ZamzamHassan-zo7jo
    @ZamzamHassan-zo7jo 7 หลายเดือนก่อน

    Cannot downloaded why😢😊

  • @mnaveed6866
    @mnaveed6866 3 ปีที่แล้ว +1

    Respectfully and gain knowledge

  • @ramanahlawat398
    @ramanahlawat398 4 ปีที่แล้ว +3

    HNO3 acts as a bronsted base

  • @BeepingSheep
    @BeepingSheep 6 ปีที่แล้ว +2

    How did the carbocation get it's charge? There are only three bonds
    Edit: Time stamp: 4:03

    • @mahdiabdullahnoman3573
      @mahdiabdullahnoman3573 6 ปีที่แล้ว +2

      , when the nitroniumion is attacking the ring with a positive charge, it gets nurtilized by giving the positive charge to the ring.
      Therefore it will from crabocation.

    • @BeepingSheep
      @BeepingSheep 6 ปีที่แล้ว +1

      Mahdi Abdullah Noman It took a while, but I see it now. Thanks

  • @paoloemilioregno1576
    @paoloemilioregno1576 5 ปีที่แล้ว +2

    Does this reaction require sulfuric acid? Or could nitric acid react with itself in the first step?

    • @abdelrahimhajelnour7682
      @abdelrahimhajelnour7682 5 ปีที่แล้ว +2

      It requires sulphuric acid to help nitric acid forming an electrophile

  • @JP11994
    @JP11994 6 ปีที่แล้ว +5

    Hey O chem tutor, if I were to join your pateron membership would you be open to suggestion of video topics in o chem? There are very few videos on organometallics reactions like, suzuki reactions , heck reactions, tsuji-trost reactions, stile reactions, songashira reactions, and olefin metathesis that you can find on youtube. It would be awesome if you could make videos on these. Thank you.

  • @mahinhasan-dk1lq
    @mahinhasan-dk1lq ปีที่แล้ว

    Make more videos

  • @Qaiou
    @Qaiou 11 หลายเดือนก่อน

    ok i kinda get it

  • @ManojKumar-oi5ee
    @ManojKumar-oi5ee 5 ปีที่แล้ว +4

    I have an doubt. How the benzene hv one more hydrogen .
    Time stamp:2:58

    • @zockertwins
      @zockertwins 5 ปีที่แล้ว +4

      There is a hydrogen on every carbon atom, he didn't bother drawing all 6 and just drew 2.

  • @rambles2727
    @rambles2727 4 หลายเดือนก่อน

    "LOl Do ToLuEnE NeXT"

  • @D-ali
    @D-ali 3 ปีที่แล้ว +1

    احسنت كلشي مافهمت

  • @SatyamKumar-gy3tl
    @SatyamKumar-gy3tl 10 หลายเดือนก่อน +1

    Abhi tak ka sabae bakwaas video 💯💯💯

  • @_gammingsultan7162
    @_gammingsultan7162 5 ปีที่แล้ว +1

    😍😍😍

  • @Qaiou
    @Qaiou 11 หลายเดือนก่อน

    :(

  • @lovefoodc30000
    @lovefoodc30000 10 หลายเดือนก่อน

    Chemistry is bad thing 😭😭😭😭