NMR Analysis - Assigning a Spectrum and Predicting a Structure (Harder Version)

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  • เผยแพร่เมื่อ 2 ก.ค. 2024

ความคิดเห็น • 33

  • @fenjahamdir349
    @fenjahamdir349 4 หลายเดือนก่อน +1

    That was very interesting to watch. I would have guessed the structure just based on the LiAlH4 and it is so interesting to see it proven with the NMR-Spectra.

  • @hungnguyen-hl4ot
    @hungnguyen-hl4ot 7 ปีที่แล้ว +1

    Thanks Dr Tony St. John. Video is very interesting example. You may be up NMR spectrum example. I can print NMR spectrum and practice

  • @ilkerertosun6593
    @ilkerertosun6593 4 ปีที่แล้ว +1

    i now it's a bit late to say but i really enjoy watching uv nmr predictions. İf u are still filming this type of videos, i would like to watch some cosy and hetcor nmr participated assigning 'couse i'm a bit bad at reading those two of them. i wish u good luck :)

  • @26d8
    @26d8 3 ปีที่แล้ว +7

    Much appreciated, well explained, is it possible for you tl make more videos on NMR, splitting patterns , chemical shifts, coupling constants, sterochemical inequivalence?
    :)

  • @BATOOLMEHDI
    @BATOOLMEHDI 2 ปีที่แล้ว +1

    Thank you for such a informative video 👍

  • @annaberlin4008
    @annaberlin4008 16 วันที่ผ่านมา

    Thank you!😃✨

  • @kalkidanberhanu7708
    @kalkidanberhanu7708 4 ปีที่แล้ว +1

    bless you.

  • @plamenpenchev262
    @plamenpenchev262 6 หลายเดือนก่อน

    As a professional I solved B structure in a minute or two, without pen and paper, but I want to add some remarks.
    1. Without area under signals is more resembling Agatha Cristies' stupid novel.
    2. When solving such problems with my students we use additionally additive rules for calculating chem shift, e.g. those in Pretsch book (Structure determination of organic compounds, Springer).
    Nevertheless, I appreciate your efford and like your channel.

  • @user-ff4wc9ev8x
    @user-ff4wc9ev8x ปีที่แล้ว

    I appreciate , well explained. just I couldn't figure out why e is not located between f & d as its closer to O than d, so it gotta be in down field.

  • @hegebjelland8384
    @hegebjelland8384 6 ปีที่แล้ว

    Thank you, lots of good advice :)

  • @elifpolat4220
    @elifpolat4220 3 ปีที่แล้ว +1

    Thank you for lesson, your lesson is really enlightened me. Because I watched lots of video about in this topic, but your video is best.

  • @charanjitkaur4707
    @charanjitkaur4707 4 ปีที่แล้ว

    Sir, Can you discuss NMR spectrum of some flavones and isoflavones?

  • @zweetentation
    @zweetentation 4 ปีที่แล้ว +1

    My hardest excercise :( my own monster-molecule of my thesis. Really trying to get it, wish me luck.

  • @missnoodlebrain
    @missnoodlebrain 5 ปีที่แล้ว +16

    why did you put c & d downfield when you said they should be upfield ( downfield is shifting toward left and up field is shifting toward right closer to 0)

    • @ziyingzhou1546
      @ziyingzhou1546 3 ปีที่แล้ว

      i also feel puzzled

    • @michellla93
      @michellla93 3 ปีที่แล้ว

      @@ziyingzhou1546 I think he is saying c should be more downfield than b due to conjugation

    • @blackf.5242
      @blackf.5242 2 ปีที่แล้ว

      Yeah, it should be the Opposite

  • @chemistryQB
    @chemistryQB 5 หลายเดือนก่อน

    ❤ helpful Video
    India🇮🇳

  • @moustafaelawamy3240
    @moustafaelawamy3240 6 ปีที่แล้ว +2

    Sorry i just cant figure out how the OH peak appears at this range in compound A ?

    • @TonyStJohn
      @TonyStJohn  6 ปีที่แล้ว +2

      Hi Mostafa, OH proton peaks will commonly move around/broaden a bit due to different solvents/proton exchange, etc.

    • @moustafaelawamy3240
      @moustafaelawamy3240 6 ปีที่แล้ว

      thanks a lot

  • @anniehart5433
    @anniehart5433 4 ปีที่แล้ว

    ceo of "stickies"

  • @geanellavera-avellan9431
    @geanellavera-avellan9431 6 ปีที่แล้ว

    awesome video but how do you know when it is 2H, 3H etc?

    • @TonyStJohn
      @TonyStJohn  6 ปีที่แล้ว +1

      Geanella Vera-Avellan great question! A lot of the time that info will be provided in the problem. But in reality, you would have to find the area under each peak (yay calculus!) We would typically set the area of the smallest looking peak to 1, and then all the larger peaks are just a ratio of that original, smallest peak. In this problem however, it looks like I just estimated what the relative peak areas are. Once you see enough spectra the areas will start jumping out a little more!

  • @emmapaulus99
    @emmapaulus99 5 ปีที่แล้ว

    god bless

  • @ahmedmamduh9197
    @ahmedmamduh9197 ปีที่แล้ว

    I don't understand. Shouldnt the aromatics also be experiencing meta coupling?

  • @janmajoybanerjee3032
    @janmajoybanerjee3032 11 วันที่ผ่านมา

    @4.25 you said 3high multiplet instead of 2 high multiplet ( e)

  • @praneshbalasubramaniam6669
    @praneshbalasubramaniam6669 2 ปีที่แล้ว

    I wish you were my teacher

  • @user-jy4ok4kk7v
    @user-jy4ok4kk7v 28 วันที่ผ่านมา

    hi,, i need you help,, can u help me to fine my own structur... i try to intrepretation but can not

  • @danielpark1287
    @danielpark1287 ปีที่แล้ว

    😊

  • @Jenna-vj2ju
    @Jenna-vj2ju หลายเดือนก่อน

    Why is c more downfield?

  • @user-cu8lj1yy4j
    @user-cu8lj1yy4j 3 ปีที่แล้ว

    Can you please help me draw the structure for a compound. 🙏🏻🙏🏻🙏🏻 please give me your email