TiCl4 Titanium tetrachloride: The most fuming liquid
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- เผยแพร่เมื่อ 10 ก.พ. 2018
- This video about Titanium tetraсhloride (TiCl4) and reactions with it.
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Reaction timing:
1:35 TiCl4 on the air
2:29 TiCl4 solid
2:57 Ti + Cl2(liq.)
3:59 Ti + Cl2(liq.) slowmo
5:05 TiCl4 add to H2O
5:37 H2O add to TiCl4
6:22 NH3·H2O + TiCl4 (solid)
6:57 NH3·H2O + TiCl4
8:15 TiCl4 + NaBH4
9:06 TiCl4 + NaBH4 slowmo
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Thanks for watching! - วิทยาศาสตร์และเทคโนโลยี
Holy shit the cleanup must be unreal. TiO2 on EVERYTHING WITHIN SIGHT.
Wow that part with mixing of aqueous ammonia and the resultant snowflakes really blew my mind!
Excellent video a real one of a kind!
thx! I want to make a big smoky explosion using these reagents
Ammonia is my favourite reaction.
Yay for salty snow.
Ammonia is gayyyyyy
If you ever use this stuff again (one of my least favourite chemicals to use), making TiCl4(THF)2 is a really nice demo.
This looks like the only chemical that's fun just taking the cap off.
@@-danR DAST is worse, cos HF fumes.
It literally couldn't smoke enough probably the best demonstration for saturation, I ever seen.
all around one of my favorite experiments. So glad I found this.
I'm catching up on older videos. And this by far is my fav! I love how you, Feliks, talk to us between reactions.
YOUR CHANNEL IS GOLD
thx! now we prepare the second season, it will be osmium! :)
ChemicalForce That sounds awesome, I'm excited. Question - where do you get your chemicals from? There are some really exotic ones!
we worked in supply of chemical reagents, and some chemicals left in stock, some buy for video, we have a good partnerships in that sector ;)
@@ChemicalForce do you know where to get osmium tetraoxide?I mean for as cheap as possible!It must have price of 12.8×0.75=9.6 US dollars per gram but it usually costs vastly more than that!
Anyway I want to repeat my own experiment with obtaining the osmium blub from it by alumothermic method!And I also by the way have to warn you just in case that upon mixing it with magnesium powder it ignites spontaneously and that causes huge disaster!Because most of OsO4 immediately evaporates and due to the unbelievable heat of reaction osmium metal boils(!!!),and obviously re-forms the oxide!
@@ChemicalForce Neat! Osmium is my favorite element, haha.
I'm fuming that I haven't found this channel until now.
Sorry for the pun I couldn't resist
This has to be my favorite of your reactions videos!.
Your channel is the home of beautiful experiments...th last one was so violent that I thought my mobile will explode after some time..great work!!
That's a beautiful reaction, I really liked the way the titanium reacted in the chlorine. I love it when stable reactions like that occur, no spitting and farting all your chemicals out the top of the test tube. The plume of TiCl4 out the top was pretty. How easy is it to condense and collect that vapor? I imagine the reaction speed would have to be carefully controlled to manage the condensation rate...
I loved the fuming thumb part!
amazing, very nice, I like it very much, congratulations
I visit your channel to see properties of such elements and compounds,those reactions are very rare to see in online
Thanks
I have been working with TiCl4, over 1,5 years in total.
Its an funny but very dangerous chemical. The company i worked for used it for glas coatings, together with other stuff such as HMDSO.
hey hiee there actually am having bit of difficulty in preparing the ticl4 solution in water ...can u please tell me how u have made its solution or diluted it in water.
@@rutujapalaskar390 You can't mix TiCl4 with water. It reacts with the water.
Interesting video and well made! :)
You are also here? Nice
That last reaction looked pretty volcanic, though I guess really more like some kind of swamp light thing.
Really great video and music!
One of the best channel 😍😍
thank you!
You deserve it
it's amazing
amazing chemical reaction...
I like your mad ideas and experiments, well done. Can you etch ceramic tiles to make them non slip with these chemicals?
Exactly as tin(IV) chloride^^ Amazing how fast they react with air.
I feel like you are my saviour today
Background music is awesome
The dog part absolutely infuriated me.
Agreed! wtf did I just see? Man that was hard to watch, thank god there was no audio. Currently fuming more than any of these reactions
Agreed. Man deserves to be hauled into court for animal abuse - disgusting.
I'm very grateful for the comments. I will not watch this video. I can't mentally handle animal abuse as it sticks in my head forever. Thank-you for the warning ⚠️⚠️⚠️⚠️🚨⚠️⚠️⚠️⚠️
It makes me so mad that YT allows this, yet news channels must say K*** just incase they get booted for saying kill. For God sales. And this Cooney girl that weighs like 2grams and mocks people who are deeply concerned?
I am deeply concerned about the disturbing ethics of the people governing what stays and what goes. Wow. Or the Ai... 👀
go back to your pills.
Wonderful
We used SiCl and GeCl in making fiberoptics. Use to burn it and collect the oxides on a ceramic rod. Than consolidate the oxides into glass..
Was pretty cool
Super!
I'm glad you do these experiments for us , I would be terrified to try some of these , but love watching them .
Do you have access to uranyl nitrate? Not thaaat interesting from a chemical point of view, but it looks really beautiful.
and would there be a way to safely show the reaction between uranyl nitrate and magnesium? That
This song is a banger man
I like these annotations you can give little factoids about what is happening, or just explain to laymen what stuff is, why they gone from the new videos? I like your outfit too btw.
I love watch your video recording
Would love to see more fluorine chemistry and reactions but I know how dangerous they are.
This music kicks ass
TiCl4 catalyzes the decomposition of aluminum hydride into aluminum metal. I studied this reaction back in grad school.
Can you recommend an acid that can dissolve tungsten? I want to see if I can make compounds from it! Thanks for any input!
Can you please demonstrate the formation of XeF4 . Thanks a lott if you do so .
I like the TiH4 and how it ignites.
Great video, the soundtrack is great
Where the hell do you get this music? I love it. It's like Doom but rocking hard
awww that bow tie... so cute :) hihihihi
Hey! How do you store the chemical after removing the syringe tab? It seems to be able to fume right out of the bottle!
Teflon or ampule
Today a syringe containing TiCl4 exploded in my hand. Thank God I was wearing safety goggles. Otherwise, I would have impaired sight...
I'd be interested in seeing the reaction between TiCl4 and NH3(l), perhaps at extremely low temperatures. (At least initially. :-) )
WTF!
That guy with the dog should be reported. You dont put dangerous chemicals on your pet. AT ALL!! 😡
TiH4 is very cool.
I’ve heard that there can be an explosive reaction between carbon tetrachloride and aluminum or sodium. I tried it with solid aluminum and aluminum powder but couldn’t get anything to happen. I didn’t try to ignite it though as I had no lighter at the time.
dontlikemath -.- The aluminium oxide layer was probably in the way
You should tell Explosions and Fire, they've got some carbon tet salvaged from an old fire extinguisher.
This stuff is like working with fogger fluid, it makes it kinda difficult to see what you're doing because everything gets surrounded in smoke, except this smoke is corrosive.
I have worked with this compound in an industry and it sucks to handle it, when it is kept open in moist air, it gives out HCl as chemforce pointed out, and forms a smokescreen
very nice vid. Do you know, why the military call it FM?
COOL VIDEO!THANKS
Shit! Why can’t I like this video a hundred times?
that is like smokebomb!
This is actually exactly what they use in smoke mortars
Can you supercool condense and pressurize to hold at standard temperature the stuff in the bottle that fumes with simple air contact?
In military operations this could be great as it would smoke screen without a thermal blindspot
I mean you could just have a chem grenade, but isn't that basically teargas and ergo a war crime to induce blindness with the teargas, or visa-versa
Pyrophorics are tight.....
What would occur if you poured TiCl4 in Oleum??, Please let me know!!
That reaction made me TiCl
I need a serious answer, how toxic is NH3-H2O + TiCl4 to people? What about TiCl4 + NaBH4? Is there a thick smoke screen that can be created that's not toxic to people?
I wonder if it is easy to reduce TiCl4 to TiCl3 and see its cool lavenders!
Ti was always strange for me. Most metal oxides when mixed with acid form a salt , TiO2 does not. I do not know any solution containing Ti4+ or Ti2+ except Titanium nitrate. I would like to see reactions of Titanium nitrate solution with different chemicals, what type of precipitates it makes, etc.
Isnt TiO2 already a salt? Or did you mean ion when talking about Ti4+/Ti2+
A couple of former colleagues of mine worked with titanium compounds, researching things like substituted titanocenes. Once the glassware had accumulated a layer of TiO2 and other crud, it was a bloody pain to try to get clean again. Most other metals' salts could be shifted with conc. nitric acid, and organic grunge could be oxidized away with stuff like conc. H2SO4 + HNO3 + a few drops of alcohol (to get things going). The titanium-based crud just sat there.
When you reacted Titanium Tetrachloride with Sodium Borohydride, it was noticeable that the orange flames didn't produce any white fumes of Titanium Oxide as you'd expect from Titanium Hydride. Do you know what was actually burning in those flames?
There are some articles that studies the use of TiCl4 in water treatment, and I'm kinda studying the mechanisms that happens when it's used in these colloidal suspensions. I live in Brazil and it is hard to find TiCl4 here.. and if I'll try to buy it the price is really expensive. So, can you tell me if it possible and viable to make solutions of TiCl4, since we can se how fuming it is? Do you know any article that specify other species formed when the reaction TiCl4 + H2O happens, besides TiOCl2 and HCl?
Thank you so much for the video!!
You may be able set up a synthesis with a source of dry chlorine, and Ti metal in a heated quartz (fused silica) tube. Then condense the output to get some crude TiCl4. If you really have to, you can distill the crude TiCl4 to purify it, if you have an airtight apparatus, very well dried and flushed with dry nitrogen gas.
If you're asking about *aqueous* solutions of TiCl4, no, that's impossible. Solutions in *dry* non-aqueous solvents are possible. It's necessary to dry them thoroughly, as TiCl4 will react instantly with any moisture present. In our lab, solvents were generally dried by refluxing over Na or K; occasionally other powerful drying agents, depending on the solvent.
My gut feeling is that any other species would rapidly disproportionate to TiCl4, TiOCl2, and TiO2, but don't hold me to that.
This was (minimally) used in a german WW2 glass grenade called Blendkorper, or Nebelflasche, used to blind vehicles, trenches, and interiors. production stopped because of the need for humidity in the air for it to work properly.
So much fyoom!
mixing liquid H2S and liquid SO2. what forms? S +ice?
Can it react with lithium aluminium hydride(diethyl ether solution)?
I like how you use way too much of the reagents and spill them all over the place. Subscribed!
Opening a jar full of TiCl4 while BattleToads && DD was playing on the background is more than epic!
This is SO awesome 😎
I always think 🤔 that if extremely fuming liquid can be extremely corrosive and oxidizer is it possible?? Can TiCl also like this only ?
Solid ttc and Liquid ttc which one moke smoke better?
can any random person buy it and if so how "safe" do you have to be around it
Forbidden vape juice
watching a video here is like playing a Vampire Survivor game
what tempreture is the titanium heated to?
Can you make colour smoke like yellow red and others with those chamicals
Used in polymer industry for catalyst manufacturing
i liked the titanium snow (time- 7:25)
I hope that dog was happily running around and not running in fear of putting that stuff on its tail?
TiCl4 is corrosive, that guy should be put in jail
@@matiszyszak4064 Did it hurt the dog?? that man is horrible
Then again, you don’t need much to produce that much fumes, so burns are unlikely, probably just irritation.
The dog would eventually lick the irritating part.
Is the reaction between TiCl4 and liquid ammonia an exothermic one?
*liquid ammonia solution! It is a very exothermic reaction!
@@ChemicalForce Thank you for your prompt response. :-)
I wonder if Titanium powder can react with Carbontetrachloride to form Titaniumtetrachloride.
It bother's me that those fumes are literally hydrochloric acid (and titanium hydroxide/titanic acid).
And TiO2 and TiOCl2.
You should get a Cronos high speed camera, there a bit expensive($2,000-$4000) but you could be the first slomo Chem channel on TH-cam
Hi! Yes! I save money for chronos2.1! But also I think about ursa g2 (120fps 4K, 300fps1080, HDR)
what happens if you pour it into molten 100% NaOH?
Is Titanium tri chloride have impurites settle down in bottom of bottle?
in an unopened TiCl4 bottle - no
what is the smoke - does it kill you?
Are you from germany ?
How does it compare to SO3?
I wonder if this chemical can be used in homemade rocket engines
Is Titanium tetrachloride flammable?
Does anybody know how respresents the reaction of TiCl4 with the moisture in the air???
btw excelent video!!!
TiCl4 + 2H2O -> TiO2 + 4HCl
I had to evacuate my garage once after dissolving Ti metal in concentrated H2SO4 created plumes of thick purple smoke lol.
Isent the fumes dangerous to breathe inn?
What famous NES game did this soundtrack come from???
where did you get such a large amount of TiCl4
Merck (or Sigma, owned by Merck)
where i can buy this chemical?
what of you have a spill how can you clean safety?
I want to see reactions of zeolite os please make vedios about it
Bur how about reactions TiCl4 with alkilamines???;)😉🤗
But what is it used for ?