@@Filipcorobivblenderi I am so sorry man, but sadly it isnt, owlcation.com/stem/Why-is-the-Sky-Blue-Hint-its-nothing-to-do-with-ozone#:~:text=The%20sky%20isn't%20blue,longer%20ones%20to%20pass%20through.
My first thought about the yellow smoke was "don't inhale the yellow smoke!", as an analogy with "don't eat yellow snow". My second thought was : could it be that a low concentration of ammonium ozonide is carried up with the other components of the smoke? One thing I love about inorganic chemistry is the amazing colours it makes. All of the organic chemistry I've done was colourful only in the ultraviolet or the infrared. Unless it went wrong. When you accidentally decompose two weeks' work with nitric acid, it goes brown.
Wow keep up these experiments! You can't even find a direct entry for "ammonium ozonide" on Wikipedia, let alone a clear picture of liquid ozone! Awesome work!
I like this guy because he is such a dedicated guy who goes into the ass hole of chemistry and find all dark and nasty reaction man i respect u ......ur a G ..O...A.......T
I didn't believe, that ammonium ozonide might even exist. That's awesome! My guess on the yellow smoke would be, that it is the ozonide, which turns into the nitrate in mid air. As far as I know, when a compound is said to be unstable at some temperatures, it doesn't mean it will not be able to form at all. It just decomposes very quickly.
Even for this channel, showing pure liquid Ozone reactions is truly unexpected. How on earth did you manage to separate the produced Ozone from the contaminating Oxygen and other gases?
there is a video by Explosions&Fire where he also made Liquid Ozone Ozon has a higher boiling point than Oxygen so you just have to boil away the Oxygen (Link if you want to see the video) th-cam.com/video/szgejoiEXP0/w-d-xo.html
@@razurio2768 Yeah I do know about that, and thinking about it I agree that's probably what he did as well. I just imagined that a lot of O2 would still be left dissolved into the liquid O3, requiring something akin to a fractional distillation to separate.
@@NormReitzel ; Did you even read the start of the paper? Also, the paper is 65 years old, but still. From the opening paragraph of the paper: "The incomplete miscibility of liquid ozone and oxygen in the temperature range of boiling liquid air has been recognized for many years. A number of physical properties of the system were investigated by Riesenfeld and Schwab. Thus the composition of the two liquid phases in equilibrium at -183°C was indicated to be 30 and 70 percent ozone, respectively. Mutual solubility increases with temperature and a value of -158°C was obtained for the consolute temperature."
@@mortlet5180 I did and the only reason that particular paper was cited is that it points out the two phases in the first 100 words or so. I never said they weren't mutually soluble. Also, if you have ever done the experiment, you would know that liquid ozone is a very dark blue, almost black. A solution of ozone in oxygen is a really pretty blue, and the liquid ozone phase is a solution of oxygen in ozone. The two are mutually soluble, but not miscible.
Deep lavender blue liquid ozone. Orange red ammonium ozonide. What a vivid contrasting color combo! Just magnificent. Superb demo of reactions most of us have never dreamed of. 👍🏻👍🏻👍🏻👍🏻👍🏻
Agreed. I would consider it the basic possibility with such a violent reaction. Though I wonder whether some other explanation may be possible. Would require quite some rigorous testing though, with quite an effort put into it, given the instability and temperature.
As always, great unusual reactions! When you talk about your ozone generator, give us a tour of your lab! I'd love to know how you do all those outlandish experiments!
Ammonia in particular is very abundant in the universe and has lots of chemically similar properties to water. Plausible that there could be life on some planets that uses ammonia as the solute medium in which metabolism takes place; in fact, on planets with a surface temperature of, say, -100 celsius, it might be the leading candidate for a liquid capable of supporting life.
Ok, now that was amazing and brave. Ammonium Ozonide is a new one on me... chemist at heart and luckily alive from all the things I tried back in the 1970s when I was a teenager. Chemistry was my hobby and back then you could buy anything. Made things like Bromine (first real experiment), chromyl chloride, hydrogen selenide, iodine chloride, tetrathionate, nitrogen tri-iodide... and survived. Keep up the good work showing things I couldn’t hope to see. Any interesting chemistry with ammonium hydrazide or pseudo halogens?
The yellow vapour produced quickly turned white so I’m presuming that the NH4 and Ozone reacted in their gaseous phases and was being quickly ejected due to the pressures produced as a result of the two liquids at slightly different temperatures meeting together.
Hi, I think that in the process of forming amonium nitrate its also form amonium nitrite, and the descomposition of nitrite forms NOx which can be the yellow smoke. I love your videos as a chemist student I am, keep going! :)
amonium nitrate also decomps and produces NOx as well. I worked at a chem plant where we produced ammonium nitrate. Fun to watch liquid ammonium nitrate teetering on the edge of being a solid and being a liquid. See the crystals form and then melt again.. several times in a 30 second span.
The reaction started with the lower temperature reaction forming NH4NO3 and oxygen so we had that white smoke. Maybe there was already NH4O3 forming at that moment and maybe it gave the smoke that yellow color. And then the reaction cooled down and the flow of steam was not strong enough to rise NH4NO3 solution anymore, so it changed its colour to white. So that's my theory, but who knows if its right or not.
Where does the extra hydrogen come from in the reaction equations? Am I missing something, or does the ammonium ozonide and ammonium nitrate reactions, as written, not balance? It is really nice to see the chemistry in action. These are compounds that I am unlikely to see otherwise. It would be nice to see the properties and reactions of the ozonides.
Good question. The reactions he shows are unbalanced. I think a better version of the first one is 2NH3 + 2O3 -> NH4NO3 + H2O + O2, which is balanced at least. No idea about the second.
The liquid ozone has an incredible color. If u got liquid O4.... it be even darker I'd imagine.. Imagine how a planet would look if it had liquid ozone oceans
I’d love to see various liquified gases: elementar gases such as Ozone, Fluor etc. And other compounds such as Sulphur-hexafluoride, Hydogen-sulphide, Oxydes of the Nitrogen, Hydrogen-fluoride, hydrogen-chloride etc. Thanks, bro! Keep this channel going...
The yellow smoke might be a smaller amount of ammonium ozonide that gets carried up with the white smoke. The color fades fast because the temperature of the smoke is increasing fast over the point at which the ammonium ozonide is no longer stable.
I think is NxOy because of the incomplete reaction of O3 and NH3 to formate Ammonium Ozonite because of the temperature nuance among both compounds surfaces
The mighty TH-cam algorithm has spoken once again. Your channel is awesome amazing. I was surprised to see you working with these two substances. We live in the Tennessee valley just kind of like the right armpit of the South we have 100 days of humidity greater than 75%, which leaves everything covered in mushrooms and mold The musky smell lingers so I've tried the ozone machine and I came up with the wild ideal. Can ozone be filtered through water and that water become charged with ozone cleaning power. ( I have purchased 40% hydrogen peroxide but it is very expensive).
Great job! Nice vid. Could you please make some Cl3N ? It is a magnificent compound, as far as I heard. Can be used in lasers as a source of high intensity light for charging.
I would like to give a suggestion Can u like mix many types of organic solvents like xylene,acetone,diethyl ether,dcm,toluene etc and try to burn it in the presence of liquid ozone
I don't think there's any danger in touching the bottom of that test tube. That is certainly not liquid ozone, but very weak solution of ozone in oxygen. Liquid ozone is a very dark violet substance. Cool video, nonetheless. This is a rare reaction and I don't remember ever seeing it online even before TH-cam existed.
Where does the proton and electron come from ? How is the ozone reduced? Skeptical......that it’s NH4 O3 (Bronsted acid adducts) and not Lewis acid adducts?
The blue color of the ozone is one of the most amazing things out there
So thats why the sky is blue? Jk i knew this but its neat seeing it up close.
So cool, I didnt know
@@cosmicrider5898 no lol, sky is blue because in white sunlight blue wavelength gets scaterred the most by our atmosphere.
@@TheArchit1 i bet ozone layer have a bit of a physical impact on blue sky. At least on a shade of a blue colour
@@Filipcorobivblenderi I am so sorry man, but sadly it isnt, owlcation.com/stem/Why-is-the-Sky-Blue-Hint-its-nothing-to-do-with-ozone#:~:text=The%20sky%20isn't%20blue,longer%20ones%20to%20pass%20through.
I'd never heard of ammonium ozonide before. I'd like to see more reactions between liquefied gases.
same
Great remark! :D
Liquid oxygen and frozen acetylene!
Obligatory link: th-cam.com/video/eXWZXXWu3AM/w-d-xo.html
@@among-us-99999 no, liquid oxygen vs liquid hydrogen.
@@ChemicalForce Does the ozonolysis of ammonia still form nitrates around 25 to 31°C?
My first thought about the yellow smoke was "don't inhale the yellow smoke!", as an analogy with "don't eat yellow snow".
My second thought was : could it be that a low concentration of ammonium ozonide is carried up with the other components of the smoke?
One thing I love about inorganic chemistry is the amazing colours it makes. All of the organic chemistry I've done was colourful only in the ultraviolet or the infrared. Unless it went wrong. When you accidentally decompose two weeks' work with nitric acid, it goes brown.
Don't inhale ANY smoke from tests.
That was my thought. Or some kind of peroxide from the experiment being wet
Man, this comment deserves much more likes that it has now.
Wow keep up these experiments! You can't even find a direct entry for "ammonium ozonide" on Wikipedia, let alone a clear picture of liquid ozone! Awesome work!
I like this guy because he is such a dedicated guy who goes into the ass hole of chemistry and find all dark and nasty reaction man i respect u
......ur a G ..O...A.......T
Well said lol
"dark and nasty" I think you mean exciting and fun.
Are u referring to Docm77, on hermitcraft 7?
This screams "fume hood", lol.
Toxic gases, explosive compound. Fume hood!
Yes, and a stable shield between you and the chemicals, when the door of the hood is opened.
@@ahmdabdallah5811, we aren't talking about religion here.
@@ahmdabdallah5811 Wrong channel buddy. I get that he deals with explosives here, but it's not THAT kind of channel.
@@ahmdabdallah5811 Get your fiction novel quotes out of here. People come here for chemistry, not to be brainwashed.
never thought I would hear the term "rapid discoloration of colouring", well I did, and it made perfect sense!
I didn't believe, that ammonium ozonide might even exist. That's awesome! My guess on the yellow smoke would be, that it is the ozonide, which turns into the nitrate in mid air. As far as I know, when a compound is said to be unstable at some temperatures, it doesn't mean it will not be able to form at all. It just decomposes very quickly.
Even for this channel, showing pure liquid Ozone reactions is truly unexpected.
How on earth did you manage to separate the produced Ozone from the contaminating Oxygen and other gases?
there is a video by Explosions&Fire where he also made Liquid Ozone
Ozon has a higher boiling point than Oxygen so you just have to boil away the Oxygen
(Link if you want to see the video) th-cam.com/video/szgejoiEXP0/w-d-xo.html
@@razurio2768 Yeah I do know about that, and thinking about it I agree that's probably what he did as well.
I just imagined that a lot of O2 would still be left dissolved into the liquid O3, requiring something akin to a fractional distillation to separate.
Pure liquid ozone is not miscible with liquid oxygen: aip.scitation.org/doi/10.1063/1.1742271
@@NormReitzel ; Did you even read the start of the paper? Also, the paper is 65 years old, but still.
From the opening paragraph of the paper:
"The incomplete miscibility of liquid ozone and oxygen in the temperature range of boiling liquid air has been recognized for many years. A number of physical properties of the system were investigated by Riesenfeld and Schwab.
Thus the composition of the two liquid phases in equilibrium at -183°C was indicated to be 30 and 70 percent ozone, respectively.
Mutual solubility increases with temperature and a value of -158°C was obtained for the consolute temperature."
@@mortlet5180 I did and the only reason that particular paper was cited is that it points out the two phases in the first 100 words or so. I never said they weren't mutually soluble. Also, if you have ever done the experiment, you would know that liquid ozone is a very dark blue, almost black. A solution of ozone in oxygen is a really pretty blue, and the liquid ozone phase is a solution of oxygen in ozone. The two are mutually soluble, but not miscible.
Deep lavender blue liquid ozone. Orange red ammonium ozonide. What a vivid contrasting color combo! Just magnificent. Superb demo of reactions most of us have never dreamed of. 👍🏻👍🏻👍🏻👍🏻👍🏻
I guess, the yellow foam has its color from ammonium ozonide, carried out of the tube together with the gases.
I was lookin to see if anyone said what I was thinking. I 2nd that idea.
Agreed. I would consider it the basic possibility with such a violent reaction. Though I wonder whether some other explanation may be possible. Would require quite some rigorous testing though, with quite an effort put into it, given the instability and temperature.
so, will there be a video on any unusual superacid like HSO3Cl, HSO3F, TfOH, SbF5 • HF, SbF5 • HSO3F?
Not quite so trivial I would guess, also given that he didnt already do it.
@@ChristianMiersch he has access to many exotic and expensive things, so maybe also to one of these?
Yo chill xD
Don't worry guys, the more subscribers and views the more complex my stuff will be
Why?
Yellow may be atomized ammonium ozonide carried up in the flow. Lower concentration would look yellow until it decomposes.
In my opinion the yellow smoke probably come as a by product reaction wich would make like NO2 or other nitrogen compounds like those
i think it was probably just aerosolized ammonium ozonide
NO2 would dimerize to colourless N2O4 at these low temperatutures.
@@Bavarianscience maybe the smoke is warmed up by the reaction, but I agree with Danielle.
2 NH3 (g) + O3 (g) → 3 H2O (l) + N2 (g) this may be N2 i think
I also think they are some gaseous nitrogen oxides
As always, great unusual reactions! When you talk about your ozone generator, give us a tour of your lab! I'd love to know how you do all those outlandish experiments!
I'm very pleased there's now video documentation of liquid ozone on TH-cam.
Excellent!
Sir, you are crazy in the best way possible. Keep up the great stuff!
It makes me wonder about the composition and chemistry on other planets.
Ammonia in particular is very abundant in the universe and has lots of chemically similar properties to water. Plausible that there could be life on some planets that uses ammonia as the solute medium in which metabolism takes place; in fact, on planets with a surface temperature of, say, -100 celsius, it might be the leading candidate for a liquid capable of supporting life.
Please do a lab/studio tour!!!
This needs upvotes
Ok, now that was amazing and brave. Ammonium Ozonide is a new one on me... chemist at heart and luckily alive from all the things I tried back in the 1970s when I was a teenager. Chemistry was my hobby and back then you could buy anything. Made things like Bromine (first real experiment), chromyl chloride, hydrogen selenide, iodine chloride, tetrathionate, nitrogen tri-iodide... and survived. Keep up the good work showing things I couldn’t hope to see. Any interesting chemistry with ammonium hydrazide or pseudo halogens?
The yellow vapour produced quickly turned white so I’m presuming that the NH4 and Ozone reacted in their gaseous phases and was being quickly ejected due to the pressures produced as a result of the two liquids at slightly different temperatures meeting together.
i think so too :)
Maybe the yellow fumes are just little Ammonium Ozonide droplets
I don't know why you don't have much subscribers but your videos are simply innovative and completely unique .
Now make some picrates. 😉
And call some FBI
Exactly!
Lead (II) picrate, please!
Do you really want my channel be banned? ;(
@@ChemicalForce make prussic acid
@@californium-2526 caesium picrate
I was actually dying for a new video of yours today🤘🤘
Your channel gets better with every video, keep up the great work!
I love how purple the ozone is.
Chemical Force Ozone Generator: An actual machine
Explosions & Fire Ozone Generator: Pile of Hazards
Perfectly balanced, as all things should be.
Nice work! It looks like cold fusion experiment!
It's unbelievable, you are brilliant chemist
The o3 seems to act like an acid. The yellow smoke may contain ammonia ozonide crystals.
My God that's so freaking cool, thank you!!!
I love the beautiful violet color of ozone! I wonder what the absorption peak is. It definitely absorbs visible light a lot more strongly than oxygen!
Hi, I think that in the process of forming amonium nitrate its also form amonium nitrite, and the descomposition of nitrite forms NOx which can be the yellow smoke. I love your videos as a chemist student I am, keep going! :)
amonium nitrate also decomps and produces NOx as well. I worked at a chem plant where we produced ammonium nitrate. Fun to watch liquid ammonium nitrate teetering on the edge of being a solid and being a liquid. See the crystals form and then melt again.. several times in a 30 second span.
Awesome experiment!
That is the most yellow of chemistry. You madman, hahaha.
i love your channel so fucking much!!! thank you so much for all your work. you're amazing, thank you for this channel!! 💕💕💕
The reaction started with the lower temperature reaction forming NH4NO3 and oxygen so we had that white smoke. Maybe there was already NH4O3 forming at that moment and maybe it gave the smoke that yellow color. And then the reaction cooled down and the flow of steam was not strong enough to rise NH4NO3 solution anymore, so it changed its colour to white. So that's my theory, but who knows if its right or not.
Fascinating.
As a fellow chemist I find this very interesting.
Keep on
Where does the extra hydrogen come from in the reaction equations? Am I missing something, or does the ammonium ozonide and ammonium nitrate reactions, as written, not balance?
It is really nice to see the chemistry in action. These are compounds that I am unlikely to see otherwise. It would be nice to see the properties and reactions of the ozonides.
Good question. The reactions he shows are unbalanced. I think a better version of the first one is 2NH3 + 2O3 -> NH4NO3 + H2O + O2, which is balanced at least. No idea about the second.
Yellow colour might be some oxide of nitrogen like nitrogen dioxide
krishna pidaparthi I think so also. Perhaps dimer of Nitrogen dioxide.
bet his nose burned after this one hahah... interesting vid!!
Can you make a video about sodium persulfate? There’s not a lot of info about it out there, but it has a handful of interesting properties
Solid ammonia Never seen that before. Yet another first on this channels. 👍
wow… awesome rare reaction!! great job!!!
Ah the best video i really wanted to watch.thanks so much dude thanks a lot.😆
The liquid ozone has an incredible color. If u got liquid O4.... it be even darker I'd imagine..
Imagine how a planet would look if it had liquid ozone oceans
Great channel!
Wow! Never heard of Ozonides before... Love the solid Ozone colour :)
My previous video was about ozonides as well, does that mean you haven't seen it yet? -_-
I’d love to see various liquified gases: elementar gases such as Ozone, Fluor etc. And other compounds such as Sulphur-hexafluoride, Hydogen-sulphide, Oxydes of the Nitrogen, Hydrogen-fluoride, hydrogen-chloride etc.
Thanks, bro! Keep this channel going...
SF6: th-cam.com/video/TNreVYIyWCE/w-d-xo.html
your experiments are epic!!
The yellow smoke could be amonium nitrante with a bit of the ozonide which would give it its yellow colour.
It's weird to watch liquid ozone interact with a non-gaseous compound without exploding
Крутейший канал... Где еще такие чудеса увидишь😳
For me the yellow is because the fume is a short-lived mixture of ammonium nitrate and ammonium ozonide
I wondered if the yellow smoke is particles of ammonium ozonide formed from the cold ozone vapour mixing with the evaporating ammonia.
Can you show us some reactions of bismuth?
Yellow smoke is probably the same reactant in the Gas Phase
The yellow smoke might be a smaller amount of ammonium ozonide that gets carried up with the white smoke. The color fades fast because the temperature of the smoke is increasing fast over the point at which the ammonium ozonide is no longer stable.
I think is NxOy because of the incomplete reaction of O3 and NH3 to formate Ammonium Ozonite because of the temperature nuance among both compounds surfaces
amazine video dude!!
I gather the yellow smoke is aerosolized ammonium ozoneide which dissapears as the tube warms up due to decomposing.
are there any transition metal ozonides that you could show us?
Hey, that's a nice demonstration
The mighty TH-cam algorithm has spoken once again. Your channel is awesome amazing.
I was surprised to see you working with these two substances.
We live in the Tennessee valley just kind of like the right armpit of the South we have 100 days of humidity greater than 75%, which leaves everything covered in mushrooms and mold
The musky smell lingers so I've tried the ozone machine and I came up with the wild ideal.
Can ozone be filtered through water and that water become charged with ozone cleaning power.
( I have purchased 40% hydrogen peroxide but it is very expensive).
0:22 Show the real and complete formulas. I can calculate them, others cannot. 😉
Greetings from a colleague of chemistry!
Would the reaction be the same if it was done in a vacuum without normal atmospheric gases around it?
Great job! Nice vid. Could you please make some Cl3N ? It is a magnificent compound, as far as I heard. Can be used in lasers as a source of high intensity light for charging.
Oh boy ammonium ozonide
I would like to give a suggestion
Can u like mix many types of organic solvents like xylene,acetone,diethyl ether,dcm,toluene etc and try to burn it in the presence of liquid ozone
lathe 1286 -- deep space rocket fuels.
@@KK-pq6lu yeah
I'm guessing the yellow vapor would be the ozonite. Also ozone won't detonate. Only rapidly decompose and boil.
if white smoke is ammonium nitrate, than could yellow smoke be ammonium ozonide and it turned white because of decomposition?..
Oh i cant believe my comments came in your videos yayyyyyy
Yeah, maybe you should comment even more often ;)
@@ChemicalForce oh definitely 😄
Explosions&Fire told me to check out your channel
what are you up to? -_-
4:20 "Yellow smoke" may be NO + O3 → NO2 + O2 or NO + O2 → NO2
It's so cool!
According to thermodynamic equilibrium calculations it could be NO2 (nitrogen dioxide).
i would love to see if LH2 and LO2 mix into each other
Gives me inspiration👌
I don't think there's any danger in touching the bottom of that test tube. That is certainly not liquid ozone, but very weak solution of ozone in oxygen. Liquid ozone is a very dark violet substance.
Cool video, nonetheless. This is a rare reaction and I don't remember ever seeing it online even before TH-cam existed.
Hi! The tip of my silicone tube that I used to condense its drops exploded when I dropped it on the table!
Waited for this.
Super reaction
Wait, that combo isn't hypergolic!? Would want a 10ft pole and blast shield to even start touching that combo!
I aspire to be a man who explains chemistry to a camera with a microphone stuck in his beard.
Yellow smoke is probably low concentration of ozonide in ammonia gas/ ammonium nitrate and water
I am studying Bsc Chemistry nd I love ur videos...🤩🤩🤩🤩🤩😁
Not a chemist by any means but could the vapors have been ozoniated amonium vapors? They did seem to decompose very quickly.
**=** For making NH4O3, I proposing to vaccum the NH3 powder and the O3 gazeous to maintain it gazeous when very cold, to react it slowly.
Beautiful ❤
I request, try you drop solid aluminium to aqua regia
Nice video
Must see Coldfire
#RealFireman
Freaking awesome.
Hence, I have subscribed 👍👍👍
Was that the article that inspired Dunkin to come up with the Snackin' Bacon menu item?
Great content, but the music was far to epic for the video.
Nice to see the deep purple colour of liquid ozone. Can you show us solid ozone?
Given that ozone is a strong oxidizer and ammonia is a reducing agent, how is it possible that ammonium ozonite exists? Is there a way to predict it?
Красивый цвет у жидкого озона!
Where does the proton and electron come from ? How is the ozone reduced? Skeptical......that it’s NH4 O3 (Bronsted acid adducts) and not Lewis acid adducts?