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One Chemistry
India
เข้าร่วมเมื่อ 5 พ.ค. 2020
Master chemistry with our engaging tutorials, expert tips, and step-by-step solutions.
Learning chemistry can be fun and simple. We believe TH-cam is Next generation TV for common public and created our channel.
Questions are best way to learn chemistry. We try to solve the questions from various examinations and provide near accurate answers.
Creator: Baskaran Ganesh Kumar
Email: suviganu@gmail.com
Address: Number 6-1344, Third Street, Asari Colony, Sivakasi, Tamil Nadu, India - 626124,
About Creator GKR : sites.google.com/view/suviganu/home
#jee #neet #neetmotivation #jeemain #jeemains #neetpreparation #neetexam #jeeadvanced #jeeexam #trb #set #setexam #setexampreparation p#net #netexam #netexampreparation #ugcnet #ugcnetexam #ugcnetjrf #chemistry #organicchemistry #inorganicchemistry #physicalchemistry #chemistryclass12 #chemistryclass11 #chemistrynotes
Learning chemistry can be fun and simple. We believe TH-cam is Next generation TV for common public and created our channel.
Questions are best way to learn chemistry. We try to solve the questions from various examinations and provide near accurate answers.
Creator: Baskaran Ganesh Kumar
Email: suviganu@gmail.com
Address: Number 6-1344, Third Street, Asari Colony, Sivakasi, Tamil Nadu, India - 626124,
About Creator GKR : sites.google.com/view/suviganu/home
#jee #neet #neetmotivation #jeemain #jeemains #neetpreparation #neetexam #jeeadvanced #jeeexam #trb #set #setexam #setexampreparation p#net #netexam #netexampreparation #ugcnet #ugcnetexam #ugcnetjrf #chemistry #organicchemistry #inorganicchemistry #physicalchemistry #chemistryclass12 #chemistryclass11 #chemistrynotes
What is Curtius Rearrangement Reaction ? Basics & Mechanism | GATE NET SET | Organic Chemistry 😊👍
For feedback and business queries, please email us at suviganu@gmail.com
Curtius Rearrangement Reaction :
The Curtius rearrangement is an organic reaction in which an acyl azide undergoes thermal decomposition to form an isocyanate intermediate, accompanied by the release of nitrogen gas. This reaction typically occurs upon heating and proceeds through a concerted mechanism, involving the migration of the acyl group from the carbonyl carbon to the adjacent nitrogen atom. The resulting isocyanate can be further hydrolyzed to yield primary amines or reacted with various nucleophiles to produce ureas, carbamates, or other derivatives.
The Curtius rearrangement holds significant importance in organic chemistry due to its versatility and efficiency in synthesizing a wide range of nitrogen-containing compounds. This reaction enables the transformation of acyl azides into highly reactive isocyanate intermediates, which can be further converted into primary amines, ureas, carbamates, and amides. Such transformations are critical in the development of pharmaceuticals, agrochemicals, and polymers. Additionally, the Curtius rearrangement proceeds under relatively mild conditions, offers high yields, and demonstrates broad functional group tolerance, making it suitable for complex molecule synthesis. Its ability to facilitate the direct conversion of carboxylic acid derivatives into valuable amine products without the need for harsh reagents or multi-step processes further underscores its importance in both academic research and industrial applications.
Mechanism:
The mechanism of the Curtius rearrangement begins with the formation of an acyl azide, typically prepared from the corresponding acyl chloride and sodium azide. Upon heating, the acyl azide undergoes decomposition, releasing nitrogen gas and generating a reactive nitrene intermediate. This intermediate quickly undergoes a 1,2-shift (migration) of the acyl group from the carbon to the nitrogen atom, leading to the formation of an isocyanate. The isocyanate can then react with water to form a primary amine through hydrolysis, or it can react with alcohols and amines to yield carbamates and ureas, respectively.
Advantages:
Versatility: The reaction offers a straightforward method for converting carboxylic acid derivatives into amines and other nitrogen-containing compounds.
High Yield: The reaction generally proceeds with good yields, especially when optimized conditions are applied.
Mild Conditions: It does not require harsh reagents, making it suitable for sensitive substrates.
Functional Group Tolerance: The reaction can be applied to a wide range of substrates with diverse functional groups.
Disadvantages:
Safety Concerns: Acyl azides are potentially hazardous due to their explosive nature, especially when handled in large quantities.
Thermal Sensitivity: The reaction requires precise temperature control to avoid decomposition or side reactions.
Limited Substrate Scope: Some sterically hindered substrates may not undergo the rearrangement efficiently.
Applications:
The Curtius rearrangement has significant applications in organic synthesis, medicinal chemistry, and pharmaceutical development. It is widely used for the synthesis of:
Primary Amines: Through hydrolysis of the isocyanate intermediate.
Ureas and Carbamates: By reaction with amines and alcohols, respectively.
Peptide Synthesis: For introducing amino groups in complex molecules.
Pharmaceutical Compounds: As a key step in the preparation of bioactive molecules, including drugs and agrochemicals.
The video may help you to learn
Curtius rearrangement mechanism
Curtius reaction synthesis
Acyl azide to isocyanate
Curtius rearrangement applications
Curtius reaction advantages and disadvantages
Organic chemistry rearrangement reactions
Isocyanate formation reaction
Curtius rearrangement examples
Primary amine synthesis reaction
Curtius rearrangement reaction conditions
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Curtius Rearrangement Reaction :
The Curtius rearrangement is an organic reaction in which an acyl azide undergoes thermal decomposition to form an isocyanate intermediate, accompanied by the release of nitrogen gas. This reaction typically occurs upon heating and proceeds through a concerted mechanism, involving the migration of the acyl group from the carbonyl carbon to the adjacent nitrogen atom. The resulting isocyanate can be further hydrolyzed to yield primary amines or reacted with various nucleophiles to produce ureas, carbamates, or other derivatives.
The Curtius rearrangement holds significant importance in organic chemistry due to its versatility and efficiency in synthesizing a wide range of nitrogen-containing compounds. This reaction enables the transformation of acyl azides into highly reactive isocyanate intermediates, which can be further converted into primary amines, ureas, carbamates, and amides. Such transformations are critical in the development of pharmaceuticals, agrochemicals, and polymers. Additionally, the Curtius rearrangement proceeds under relatively mild conditions, offers high yields, and demonstrates broad functional group tolerance, making it suitable for complex molecule synthesis. Its ability to facilitate the direct conversion of carboxylic acid derivatives into valuable amine products without the need for harsh reagents or multi-step processes further underscores its importance in both academic research and industrial applications.
Mechanism:
The mechanism of the Curtius rearrangement begins with the formation of an acyl azide, typically prepared from the corresponding acyl chloride and sodium azide. Upon heating, the acyl azide undergoes decomposition, releasing nitrogen gas and generating a reactive nitrene intermediate. This intermediate quickly undergoes a 1,2-shift (migration) of the acyl group from the carbon to the nitrogen atom, leading to the formation of an isocyanate. The isocyanate can then react with water to form a primary amine through hydrolysis, or it can react with alcohols and amines to yield carbamates and ureas, respectively.
Advantages:
Versatility: The reaction offers a straightforward method for converting carboxylic acid derivatives into amines and other nitrogen-containing compounds.
High Yield: The reaction generally proceeds with good yields, especially when optimized conditions are applied.
Mild Conditions: It does not require harsh reagents, making it suitable for sensitive substrates.
Functional Group Tolerance: The reaction can be applied to a wide range of substrates with diverse functional groups.
Disadvantages:
Safety Concerns: Acyl azides are potentially hazardous due to their explosive nature, especially when handled in large quantities.
Thermal Sensitivity: The reaction requires precise temperature control to avoid decomposition or side reactions.
Limited Substrate Scope: Some sterically hindered substrates may not undergo the rearrangement efficiently.
Applications:
The Curtius rearrangement has significant applications in organic synthesis, medicinal chemistry, and pharmaceutical development. It is widely used for the synthesis of:
Primary Amines: Through hydrolysis of the isocyanate intermediate.
Ureas and Carbamates: By reaction with amines and alcohols, respectively.
Peptide Synthesis: For introducing amino groups in complex molecules.
Pharmaceutical Compounds: As a key step in the preparation of bioactive molecules, including drugs and agrochemicals.
The video may help you to learn
Curtius rearrangement mechanism
Curtius reaction synthesis
Acyl azide to isocyanate
Curtius rearrangement applications
Curtius reaction advantages and disadvantages
Organic chemistry rearrangement reactions
Isocyanate formation reaction
Curtius rearrangement examples
Primary amine synthesis reaction
Curtius rearrangement reaction conditions
The video is Ideal for
University Chemistry Exams
Competitive Exams Like
GATE Chemistry
NET Chemical Science
UGC Chemical Science
SET Chemistry
JEE Chemistry
JAM Chemistry
NEET Chemistry
#OrganicChemistry
#ChemistryExplained
#ChemicalReactions
#LearnChemistry
#MolecularScience
#ChemistryTutorials
#ScienceExperiments
#InorganicChemistry
#PhysicalChemistry
#ChemistryFacts
#CurtiusRearrangement
#OrganicReactions
#ReactionMechanism
#IsocyanateSynthesis
#OrganicChemistryBasics
#AcylAzideReaction
#ChemistryMechanisms
#AdvancedOrganicChemistry
#AminesSynthesis
#CurtiusReactionExplained
#ChemistryExamPrep
#CompetitiveChemistry
#ChemistryMCQs
#JEEChemistry
#NEETChemistry
#ChemistryRevision
#PhysicalChemistryTricks
#OrganicChemistryShortcuts
#ChemistryStudyTips
#competitiveexampreparation
#netchemistry
#ugcchemistry
#netexam #netexampreparation #gatechemistry #gatechemistry #gateexam #gate #setexam #setexampreparation #setchemistry #jamchemistry #iit #iitjam #iitjamchemistrysyllabus #iitjamchemistry
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Very nice explanation ❤
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Amazing Sir ❤
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What will be order of basicity
The question focus is different. You cannot find trend randomly. If you find it post here
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thanks for making the vedio 🙂🙂
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
I am expecting your video all the time. Thanks
So nice of you. We will maintain our quality
🎉 thanks ❤
I'm glad you found the video helpful! 😊
Great sir yet gain best one. Can you do beckmann rearrangement
Thanks for the suggestion! I'll consider adding a video on the Beckmann rearrangement soon.
Thankyou sir..can you make E or Z enolate form respect to reaction medium...before gate net exam ... invludes lots of reagents like cy2Bcl, Lda, obub2
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
I dont see any such detailed video sir. Thanks HATs off
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
35 minutes of Beckmann. Detailed sir
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so far the best video i have ever seen. Thanks sir
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Thanks sir.
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Good work Pal. Do more work like these
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Just brilliant method of teaching ... in-depth teaching......if i succeed in my goal, I owe it to your lectures... just awesome
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Thank you sir 🎉
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
I could see your commitment sir. Thanks lot. 🎉🎉🎉❤❤❤
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Hi😅
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Thank you sir
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Buddy everything's fine Presentation, quality, transitions, etc Just the audio quality, People judge a video by audio even when the video quality is bad so make audio a priority You upload nice conten👍
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Thanks you sir really understand and useful for jee main examination
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Maximum knowledge in minimum time...thanks...this video is worth of 1 million views....
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Helped a lot
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Hi sir, nice work please arrange all the videos topic wise . So that it will be helpful to the viewer.
Your support and kind words mean a lot to us. I appreciate you taking the time to sure.. watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Hi sir, nice work please arrange all the videos topic wise . So that it will be helpful to the viewer.
Sure. Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Please post clayden examples
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I wanna send you some questions
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How to contact you sir
suviganu@gmail.com
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
@@onechemistry I have mailed you sir , can you reply me
Thank you sir
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Thank you sr.....pls make a video on hofmann,curtius,schmidt rearrangement rxn
Thanks for the suggestion! We will definitely consider making a video on those reactions in the future.
Sir please do check it question number 21. Is it right (redraw part)answer ? And thank you for uploading this video 🙏
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Very interesting
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Wow
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this could've been 10 seconds instead of 10 mins
You can always fast forward 2X and see. Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
thank you, sir❤
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I found your channel today and it looks like I'll be here with you for quite some time sir! Your channel is really amazing! Hope good students find this gem soon :D
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
Thank u soo mch sir
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Nice one good quality
Your support and kind words mean a lot to us. I appreciate you taking the time to watch our video and leave a comment. It encourages us to keep creating and improving. Grateful to have you as a viewer ! Many Thanks !
great. thanks for your effort
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Sir in fused rings , when to consider middle bond and when to not
Annuluenes we have issue. But for aromatics we mostly count it. Thanks for watching
Very detailed sir. Thanks😊
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Any jee aspirant ?
I m always waiting for your videos sir...thank u so much🎉🎉
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Fabulous ..i am subscribing your channel from my allaccount. If you make time please uplaod step by step solution of csir net 2024 exams .
Thanks for the support! I'll try my best to cover CSIR NET 2024 exam solutions in future videos.
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I never expected from this you fully satisfied sir thank you so much sir 🙏🙏🙏
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Mavalous ❤❤... great work😊
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Great video. Hats off for hard work
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4hrs😮 I will watch fully..great knowledge sharing by you..great effort sir..kudos to you👌
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hi sir we have exam on organic chemistry for assistant professor for that we need practice bits . To discus about it we sent email please reply in email. Name janaradhan reddy
😊😊
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detailed one. Could you upload power point sir. please
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